Constrained hierarchical twinning in Ru-based high temperature shape memory alloys

被引:14
作者
Manzoni, Anna M. [1 ]
Denquin, Anne [1 ]
Vermaut, Philippe [2 ,3 ]
Prima, Frederic [2 ]
Puente-Orench, Ines [4 ,5 ]
Pauly, Christoph [6 ]
Muecklich, Frank [6 ]
Portier, Richard A. [2 ]
机构
[1] Off Natl Etud & Rech Aerosp, 29 Ave Div Leclerc,BP 72, F-92322 Chatillon, France
[2] PSL Res Univ, Chim ParisTech, CNRS, IRCP, F-75005 Paris, France
[3] Univ Paris 06, Sorbonne Univ, UFR926, F-75005 Paris, France
[4] Inst Laue Langevin, 6 Rue Jules Horowitz, F-38042 Grenoble, France
[5] ICMA CSIC, Pedro Cerbuna 12, Zaragoza 50009, Spain
[6] Univ Saarland, Dept Mat Sci, Funct Mat, D-66123 Saarbrucken, Germany
关键词
Shape memory alloys; Transmission electron microscopy; EBSD; Twinning; Ru-Ta; MARTENSITIC TRANSFORMATIONS; EQUIATOMIC TARU; MICROSTRUCTURE;
D O I
10.1016/j.actamat.2016.03.067
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The microstructure of high temperature shape memory alloys of the Ru-Ta and Ru-Nb family are investigated in detail. After cooling from the high temperature cubic 13 phase the off-stoichiometric alloys show a compound twinning in the tetragonal beta' phase which prevails at room temperature and can be observed as two levels of laminates A and C [1]. The stoichiometric alloys are characterized by a second phase transformation from beta' to monoclinic beta '', which adds another type of twinning. The latter belongs to the monoclinic P2/m structure and has been created out of one of the lost symmetry elements from the tetragonal P4/mmm phase during the beta' -> beta '' transformation. The unusual characteristic of this new twinning, called B, is the fact that it has an intermediate size between the A and C twins that belong to the high-temperature transformation beta' -> beta ''. This is due to a second constrained martensitic transformation. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:283 / 296
页数:14
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