Synthesis and crystal structure of a new 3D scaffold-like compound [Mn(4,4′-bipy)(N3)2]n

被引：37
作者：
Shen, HY
Liao, DZ [1 ]
Jiang, ZH
Yan, SP
Sun, BW
Wang, GL
Yao, XK
Wang, HG
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Cent Lab, Tianjin 300071, Peoples R China
来源：
CHEMISTRY LETTERS | 1998年 / 05期
关键词：
D O I：
10.1246/cl.1998.469
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new 3D scaffold-like compound [Mn(4,4'-bipy)(N-3)(2)](n) has been synthesized and its structure determined by single-crystal X-ray analysis. The molecular structure consists of a three-dimensional network in which Mn2+ are linked by EE bridged azido ligands and 4,4'-bipy ligands. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.
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页码：469 / 470
页数：2
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