Conductive Wood for High-Performance Structural Electromagnetic Interference Shielding

被引:135
作者
Gan, Wentao [2 ]
Chen, Chaoji [2 ]
Giroux, Michael [1 ]
Zhong, Geng [2 ]
Goyal, Mukund Madhav [1 ]
Wang, Yilin [2 ]
Ping, Weiwei [2 ]
Song, Jianwei [2 ]
Xu, Shaomao [2 ]
He, Shuaiming [2 ]
Jiao, Miaolun [2 ]
Wang, Chao [1 ]
Hu, Liangbing [2 ]
机构
[1] Johns Hopkins Univ, Dept Chem & Biomol Engn, Baltimore, MD 21218 USA
[2] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA
关键词
GRAPHENE OXIDE; COMPOSITES; POLYPYRROLE; LIGHTWEIGHT; FOAM; COORDINATION; ABSORPTION; REDUCTION;
D O I
10.1021/acs.chemmater.0c01507
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electric conductors are ubiquitously used for electromagnetic shielding, flexible electronics, and energy storage, with metals and carbon-based compounds as traditional choices for these applications. Here, we develop a conductive wood as a new type of structural electromagnetic interference (EMI) shielding material with combined load-bearing function via delignification and subsequent in situ chemical vapor deposition of polypyrrole (PPy) inside the wood channels. The centimeter-long wood channels are well coated by a layer of interconnected PPy, which provides a high electrical conductivity of 39 S m(-1). Our results demonstrate that 3.5 cm thick conductive wood displays an EMI shielding effectiveness of similar to 58 dB. Moreover, the conductive wood inherits the advanced mechanical strength of natural wood via the carbonization-free process, as the compressive and tensile strengths of the conductive wood are about 3- and 28.7-times higher than those of conventional carbonized wood materials, respectively. This study may pave the way for structural EMI shielding applications using scalable, renewable, and cost-effective biomaterials. Its remarkable advantages, including uniform electrical conductivity, outstanding compressive strength, a controllable material thickness of up to several centimeters, as well as its lightweight and sustainability, ensure strong potential for applications in next-generation structural materials.
引用
收藏
页码:5280 / 5289
页数:10
相关论文
共 56 条
[1]   Recent advances in carbon-based polymer nanocomposites for electromagnetic interference shielding [J].
Abbasi, Hooman ;
Antunes, Marcelo ;
Ignacio Velasco, Jose .
PROGRESS IN MATERIALS SCIENCE, 2019, 103 :319-373
[2]   Bioinspired Wood Nanotechnology for Functional Materials [J].
Berglund, Lars A. ;
Burgert, Ingo .
ADVANCED MATERIALS, 2018, 30 (19)
[3]   Electrically conducting biodegradable polymer composites (polylactide-polypyrrole and polycaprolactone-polypyrrole) for passive resonant circuits [J].
Boutry, Clementine M. ;
Gerber-Hoerler, Isabel ;
Hierold, Christofer .
POLYMER ENGINEERING AND SCIENCE, 2013, 53 (06) :1196-1208
[4]   Environmentally friendly reduction of a platinum catalyst precursor supported on polypyrrole [J].
Buitrago-Sierra, Robison ;
Jesus Garcia-Fernandez, M. ;
Mercedes Pastor-Blas, M. ;
Sepulveda-Escribano, Antonio .
GREEN CHEMISTRY, 2013, 15 (07) :1981-1990
[5]   Scalable and Sustainable Approach toward Highly Compressible, Anisotropic, Lamellar Carbon Sponge [J].
Chen, Chaoji ;
Song, Jianwei ;
Zhu, Shuze ;
Li, Yiju ;
Kuang, Yudi ;
Wan, Jiayu ;
Kirsch, Dylan ;
Xu, Lisha ;
Wang, Yanbin ;
Gao, Tingting ;
Wang, Yilin ;
Huang, Hao ;
Gan, Wentao ;
Gong, Amy ;
Li, Teng ;
Xie, Jia ;
Hu, Liangbing .
CHEM, 2018, 4 (03) :544-554
[6]  
Chen CJ, 2017, ENERG ENVIRON SCI, V10, P538, DOI [10.1039/c6ee03716j, 10.1039/C6EE03716J]
[7]   Synergistically assembled MWCNT/graphene foam with highly efficient microwave absorption in both C and X bands [J].
Chen, Honghui ;
Huang, Zhiyu ;
Huang, Yi ;
Zhang, Yi ;
Ge, Zhen ;
Qin, Bin ;
Liu, Zunfeng ;
Shi, Qian ;
Xiao, Peishuang ;
Yang, Yang ;
Zhang, Tengfei ;
Chen, Yongsheng .
CARBON, 2017, 124 :506-514
[8]   Enhanced electromagnetic interference shielding efficiency of polystyrene/graphene composites with magnetic Fe3O4 nanoparticles [J].
Chen, Yu ;
Wang, Yongli ;
Zhang, Hao-Bin ;
Li, Xiaofeng ;
Gui, Chen-Xi ;
Yu, Zhong-Zhen .
CARBON, 2015, 82 :67-76
[9]   Lightweight and Flexible Graphene Foam Composites for High-Performance Electromagnetic Interference Shielding [J].
Chen, Zongping ;
Xu, Chuan ;
Ma, Chaoqun ;
Ren, Wencai ;
Cheng, Hui-Ming .
ADVANCED MATERIALS, 2013, 25 (09) :1296-1300
[10]   COVID-19 Government Response Event Dataset (CoronaNet v.1.0) [J].
Cheng, Cindy ;
Barcelo, Joan ;
Hartnett, Allison Spencer ;
Kubinec, Robert ;
Messerschmidt, Luca .
NATURE HUMAN BEHAVIOUR, 2020, 4 (07) :756-+