Synthesis and Spectroscopic Characterization of Diphenylargentate, [(C6H5)2Ag]-

被引：15
作者：
Roehr, M. I. S. [2 ]
Petersen, J. [1 ]
Brunet, C. [3 ]
Antoine, R. [3 ]
Broyer, M. [3 ]
Dugourd, P. [3 ]
Bonacic-Koutecky, V. [2 ,4 ]
O'Hair, R. A. J. [5 ]
Mitric, R. [1 ]
机构：
[1] Free Univ Berlin, Fachbereich Phys, D-14195 Berlin, Germany
[2] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
[3] Univ Lyon 1, CNRS, F-69622 Villeurbanne, France
[4] Univ Split, Interdisciplinary Ctr Adv Sci & Technol, HR-21000 Split, Croatia
[5] Univ Melbourne, ARC Ctr Excellence Free Rad Chem & Biotechnol, Inst Mol Sci & Biotechnol Bio21, Sch Chem, Melbourne, Vic 3010, Australia
来源：
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2012年 / 3卷 / 09期
关键词：
GAS-PHASE SYNTHESIS; CHARGE-TRANSFER; INFRARED-SPECTROSCOPY; ELECTRON LOCALIZATION; BOND FORMATION; DISSOCIATION; ABSORPTION; REACTIVITY; COMPLEXES; CHEMISTRY;
D O I：
10.1021/jz300280f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present the structural and optical properties of the isolated diphenylargentate anion, which has been synthesized by multistage mass spectrometry in a quadrupole ion trap. The experimental photodetachment spectrum has been obtained by action spectroscopy. Comparison with quantum chemical calculations of the electronic absorption spectrum allows for a precise characterization of the spectroscopic features, showing that in the low-energy regime, the optical properties of diphenylargentate bear a significant resemblance to those of atomic silver.
引用
收藏
页码：1197 / 1201
页数：5
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