Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes

被引：190

作者：

Liu, ZJ ^{[1
]}

Larock, RC ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 38期

关键词：

D O I：

10.1021/ja054079p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N σ-bond addition of amides and S-N σ-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided. Copyright © 2005 American Chemical Society.

引用

页码：13112 / 13113

页数：2

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