Plasma ash processing solutions for advanced interconnect technology

被引:8
作者
Fuller, N. C. M. [1 ]
Worsley, M. A. [2 ]
Tai, L. [3 ]
Bent, S. [4 ]
Labelle, C. [5 ]
Arnold, J. [6 ]
Dalton, T. [1 ]
机构
[1] IBM Corp, Div Res, TJ Watson Res Ctr, Yorktown Hts, NY 10598 USA
[2] Stanford Univ, Stanford, CA 94305 USA
[3] IBM Corp, Syst & Technol Grp, Hopewell Jct, NY 12533 USA
[4] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[5] Adv Micro Devices Inc, Hopewell Jct, NY 12533 USA
[6] IBM Res Div, Semicond Res & Dev Ctr, Albany, NY 12222 USA
关键词
plasma modification; ion current; porous SiCOH dielectrics; downstream plasmas;
D O I
10.1016/j.tsf.2007.08.071
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A mechanism for the modification of porous ultra low-k (ULK) and extreme ultra low-k (EULK) SiCOH-based materials is proposed. This is achieved by correlating film damage on a patterned structure measured by angular resolved x-ray photoelectron spectroscopy (ARXPS) with corresponding changes in reactive species radical density and ion current in the plasma measured by optical emission spectroscopy (OES), rare gas actinometry, and modeling. Line-to-line electrical leakage and capacitance data of nested line structures exposed to downstream ash plasmas suggest that other etching steps during back-end-of-the-line (BEOL) dual damascene processing are also critical for the overall modification induced to these materials. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:3558 / 3563
页数:6
相关论文
共 12 条
[1]  
FULLER N, COMMUNICATION
[2]  
FULLER NCM, 2005, P ECS 2005 INT SEM T, P299
[3]  
FULLER NCM, 2006, P IEEE IITC, P21
[4]   Material modification of the patterned wafer during dry etching and strip determined by XPS [J].
Furukawa, Y ;
Patz, M ;
Kokubo, T ;
Snijders, JHM .
MICROELECTRONIC ENGINEERING, 2003, 70 (2-4) :267-273
[5]  
*ITRS, 2001, INT TECHN ROADM SEM
[6]   Optimization of etching and stripping chemistries for Z3MS™ low-k [J].
Lepage, M ;
Shamiryan, D ;
Baklanov, M ;
Struyf, H ;
Mannaert, G ;
Vanhaelemeersch, S ;
Weidner, K ;
Meynen, H .
PROCEEDINGS OF THE IEEE 2001 INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE, 2001, :174-176
[7]   Dry ashing process evaluation for porous ULK films [J].
Louveau, O ;
Bourlot, C ;
Marfoure, A ;
Kalinovski, I ;
Su, J ;
Hills, G ;
Louis, D .
MICROELECTRONIC ENGINEERING, 2004, 73-4 :351-356
[8]   Integration damage in organosilicate glass films [J].
Ryan, ET ;
Martin, J ;
Junker, K ;
Lee, JJ ;
Guenther, T ;
Wetzel, J ;
Lin, S ;
Gidley, DW ;
Sun, JN .
PROCEEDINGS OF THE IEEE 2002 INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE, 2002, :27-29
[9]   Comparative study of SiOCH low-k films with varied porosity interacting with etching and cleaning plasma [J].
Shamiryan, D ;
Baklanov, MR ;
Vanhaelemeersch, S ;
Maex, K .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2002, 20 (05) :1923-1928
[10]   Effect of radical species density and ion bombardment during ashing of extreme ultralow-κ interlevel dielectric materials [J].
Worsley, M. A. ;
Bent, S. F. ;
Fuller, N. C. M. ;
Tai, T. L. ;
Doyle, J. ;
Rothwell, M. ;
Dalton, T. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (01)