Electric-Field-Responsive Handle for Large-Area Orientation of Discotic Liquid-Crystalline Molecules in Millimeter-Thick Films

被引：66

作者：

Miyajima, Daigo ^{[2
]}

Araoka, Fumito ^{[1
]}

Takezoe, Hideo ^{[1
]}

Kim, Jungeun ^{[3
]}

Kato, Kenichi ^{[4
]}

Takata, Masaki ^{[4
]}

Aida, Takuzo ^{[2
]}

机构：

[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

[2] Univ Tokyo, Dept Chem & Biotechnol, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

[3] Japan Synchrotron Radiat Res Inst JASRI, Sayo, Hyogo 6795148, Japan

[4] RIKEN SPring 8 Ctr, Sayo, Hyogo 6795148, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 34期

关键词：

hydrogen bonds; liquid crystals; self-assembly; semiconductors; supramolecular chemistry; COLUMNAR SUPERSTRUCTURE; HOMEOTROPIC ALIGNMENT; UNIAXIAL ALIGNMENT; TRANSISTOR; MOBILITY; PHASE; HEXABENZOCORONENE; TRANSITION; MESOPHASE;

D O I：

10.1002/anie.201102472

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Current events: An electric-field-responsive handle (see picture) was developed that enables large-area and millimeter-thick unidirectional orientation of columnarly assembled π-conjugated liquid-crystalline molecules. The handles in the columns are hydrogen-bonded and align along the direction of an applied electric field. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：7865 / 7869

页数：5

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