Syntheses, crystal structures and properties of dinuclear copper(I) complexes

被引：9

作者：

Tan, Chun-Hong ^{[1
]}

Ma, Xiao ^{[1
]}

Zhu, Qi-Long ^{[1
]}

Huang, Yi-Hui ^{[1
]}

Fu, Rui-Biao ^{[1
]}

Hu, Sheng-Min ^{[1
]}

Sheng, Tian-Lu ^{[1
]}

Wu, Xin-Tao ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2012年 / 1007卷

关键词：

Copper(I) compounds; Crystal structure; Intramolecular organic sandwich; Second-order nonlinear optical effect; Photoluminescence; RESONANCE RAMAN; MAGNETIC-PROPERTIES; FRAMEWORKS; BR;

D O I：

10.1016/j.molstruc.2011.09.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two dinuclear molecule-bridged Cu(I) complexes, (mu-bpym)[Cu(PPh3)Cl](2) (1). [(mu-bpym)(CuL)(2)] (ClO4)(2)center dot(CH3CN)(2)(H2O) (2) (bpym = 22'-bipyrimidine, L= (R)-(+)-2,2'-bis(diphenylphospho)-1,1'-dinaphthalene) have been synthesized and characterized. The molecular structures of the two new dinuclear compounds exhibit bridging of two copper(I) centers by the symmetrically bis-chelating bpym ligand. Intriguingly, compound 1 features a remarkable "intramolecular organic sandwich" configuration where the central 2,2'-bipyrimidine bridging ligand interacts in pi/pi/pi fashion with two phenyl rings from the coligands above and below the central plane, while chiral compound 2 exhibits second-order nonlinear optical effect and temperature-dependent luminescence. Upon decreasing the temperature from 298 to 10K, compound 2 shows a red light emission. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：26 / 30

页数：5

共 37 条

[11] 2,2'-BIPYRIMIDINE (BIPYM)-BRIDGED DINUCLEAR COMPLEXES .4. SYNTHESIS, CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [CO2(H2O)8(BIPYM)][NO3]4, [CO2(H2O)8(BIPYM)][SO4]2.2H2O AND [CO2(BIPYM)3(NCS)4] [J].