A Linear Piperazine-Containing Ligand and Its Hg Coordination Polymer

被引：0
|
作者：
Chu, Wen-Juan [1 ]
Li, Rui-Jun [1 ]
Fan, Yao-Ting [1 ]
Hou, Hong-Wei [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 01期
基金：
中国国家自然科学基金;
关键词：
crystal structure; luminescence property; polymer; solid-state UV-Vis; ORGANIC FRAMEWORKS; METAL; UNITS; TRINUCLEAR; CONVERSION; BINUCLEAR; COMPLEXES; CHEMISTRY; SALTS;
D O I：
10.1080/15533174.2011.609220
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of piperazine hexahydrate with triazol and paraformaldehyde afford a new piperazine-containing ligand: (N,N'-bis(1-H-1,2,4-triazole-1-yl) piperazine) (btp). X-ray crystal diffraction reveals that btp is an overall linear structure. Its Hg2+ polymer displays a zigzag chain in which piperazine is held in the chair conformation. In addition, the spectra properties of the btp and 1 are investigated, the strong luminescence characteristics of btp and 1 are found.
引用
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页码：9 / 13
页数：5
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