Measurement Protocols for Reporting PEDOT Thin Film Conductivity and Optical Transmission: A Critical Survey

被引：26

作者：

Fabretto, Manrico ^{[1
,2
]}

Zuber, Kamil ^{[1
]}

Jariego-Moncunill, Carlos ^{[1
]}

Murphy, Peter ^{[1
]}

机构：

[1] Univ S Australia, Mawson Inst, Mawson Lakes, SA 5095, Australia

[2] Univ S Australia, Ian Wark Res Inst, Mawson Lakes, SA 5095, Australia

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2011年 / 212卷 / 19期

关键词：

conducting polymers; conductivity; optical transmission; poly(3,4-ethylenedioxythiopnene) (PEDOT); thin films; VAPOR-PHASE POLYMERIZATION; DOPED POLY(3,4-ETHYLENEDIOXYTHIOPHENE); ELECTROCHROMIC DEVICES; POLYMERS; POLYANILINE; SENSORS; ENHANCEMENT; ELECTRONICS; ATTENUATOR; DISPLAYS;

D O I：

10.1002/macp.201100303

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

PEDOT is one of the most frequently studied conducting polymers in literature but values for optical transmission and electrical conductivity vary greatly. Therefore measurement protocols are examined and insights are suggested into why the protocols themselves may lead to differences. Reported PEDOT conductivity is the result of contact and non-contact film thickness and four-point probe measurements. The soft nature of PEDOT implies that any contact method must be executed with extreme care as values of conductivity ranging from 780 to 2 775 S.cm(-1) can be obtained. Similarly, variations in the optical minimum, maximum, and transmission range are found based on different switching voltage protocols. The results present here highlight the need for explicitly stating the measurement protocol used.

引用

页码：2173 / 2180

页数：8

共 50 条

[31] Oxidative chemical vapor deposition of electrically conducting poly(3,4-ethylenedioxythiophene) films
Lock, John P.
Im, Sung Gap
Gleason, Karen K.
[J]. MACROMOLECULES, 2006, 39 (16) : 5326 - 5329
[32] Prospects of conducting polymers in biosensors
Malhotra, Bansi D.
Chaubey, Asha
Singh, S. P.
[J]. ANALYTICA CHIMICA ACTA, 2006, 578 (01) : 59 - 74
[33] An unusual electrochromic device based on a new low-bandgap conjugated polymer
Meng, H
Tucker, D
Chaffins, S
Chen, YS
Helgeson, R
Dunn, B
Wudl, F
[J]. ADVANCED MATERIALS, 2003, 15 (02) : 146 - +
[34] High contrast solid-state electrochromic devices from substituted 3,4-propylenedioxythiophenes using the dual conjugated polymer approach
Padilla, Javier
Seshadri, Venkataramanan
Filloramo, James
Mino, Warren K.
Mishra, Sarada P.
Radmard, Bijan
Kumar, Anil
Sotzing, Gregory A.
Otero, Toribio F.
[J]. SYNTHETIC METALS, 2007, 157 (6-7) : 261 - 268
[35] Classification of red wines by chemometric analysis of voltammetric signals from PEDOT-modified electrodes
Pigani, L.
Foca, G.
Ulrici, A.
lonescu, K.
Martina, V.
Terzi, F.
Vignali, M.
Zanardi, C.
Seeber, R.
[J]. ANALYTICA CHIMICA ACTA, 2009, 643 (1-2) : 67 - 73
[36] All-plastic electrochromic devices based on PEDOT as switchable optical attenuator in the near IR
Pozo-Gonzalo, Cristina
Mecerreyes, David
Pomposo, Jose A.
Salsamendi, Maltane
Marcilla, Rebeca
Grande, Hans
Vergaz, Ricardo
Barrios, David
Sanchez-Pena, Jose M.
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (02) : 101 - 106
[37] Electrochemical sensors based on conducting polymer- polypyrrole
Ramanavicius, A.
Ramanaviciene, A.
Malinauskas, A.
[J]. ELECTROCHIMICA ACTA, 2006, 51 (27) : 6025 - 6037
[38] Spray coatable electrochromic dioxythiophene polymers with high coloration efficiencies
Reeves, BD
Grenier, CRG
Argun, AA
Cirpan, A
McCarley, TD
Reynolds, JR
[J]. MACROMOLECULES, 2004, 37 (20) : 7559 - 7569
[39] SPECIFIC CONTACT RESISTANCE USING A CIRCULAR TRANSMISSION-LINE MODEL
REEVES, GK
[J]. SOLID-STATE ELECTRONICS, 1980, 23 (05) : 487 - 490
[40] X-ray diffraction and scanning electron microscopic studies on the crystal structure and surface/interface morphology of zinc-octaethylporphyrin films on an indium tin oxide substrate spin coated with 3,4-polyethylenedioxythiophene:polystyrenesulfonate
Ryuzaki, S.
Onoe, J.
[J]. JOURNAL OF APPLIED PHYSICS, 2009, 106 (02)

← 1 2 3 4 5 →