Measurement Protocols for Reporting PEDOT Thin Film Conductivity and Optical Transmission: A Critical Survey

被引：26

作者：

Fabretto, Manrico ^{[1
,2
]}

Zuber, Kamil ^{[1
]}

Jariego-Moncunill, Carlos ^{[1
]}

Murphy, Peter ^{[1
]}

机构：

[1] Univ S Australia, Mawson Inst, Mawson Lakes, SA 5095, Australia

[2] Univ S Australia, Ian Wark Res Inst, Mawson Lakes, SA 5095, Australia

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2011年 / 212卷 / 19期

关键词：

conducting polymers; conductivity; optical transmission; poly(3,4-ethylenedioxythiopnene) (PEDOT); thin films; VAPOR-PHASE POLYMERIZATION; DOPED POLY(3,4-ETHYLENEDIOXYTHIOPHENE); ELECTROCHROMIC DEVICES; POLYMERS; POLYANILINE; SENSORS; ENHANCEMENT; ELECTRONICS; ATTENUATOR; DISPLAYS;

D O I：

10.1002/macp.201100303

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

PEDOT is one of the most frequently studied conducting polymers in literature but values for optical transmission and electrical conductivity vary greatly. Therefore measurement protocols are examined and insights are suggested into why the protocols themselves may lead to differences. Reported PEDOT conductivity is the result of contact and non-contact film thickness and four-point probe measurements. The soft nature of PEDOT implies that any contact method must be executed with extreme care as values of conductivity ranging from 780 to 2 775 S.cm(-1) can be obtained. Similarly, variations in the optical minimum, maximum, and transmission range are found based on different switching voltage protocols. The results present here highlight the need for explicitly stating the measurement protocol used.

引用

页码：2173 / 2180

页数：8

共 50 条

[1] n- and p-doped poly(3,4-ethylenedioxythiophene): Two electronically conducting states of the polymer
Ahonen, HJ
Lukkari, J
Kankare, J
[J]. MACROMOLECULES, 2000, 33 (18) : 6787 - 6793
[2] Andersson P, 2002, ADV MATER, V14, P1460, DOI 10.1002/1521-4095(20021016)14:20<1460::AID-ADMA1460>3.0.CO
[3] 2-S
[4] Multicolored electrochromism polymers: Structures and devices
Argun, AA
Aubert, PH
Thompson, BC
Schwendeman, I
Gaupp, CL
Hwang, J
Pinto, NJ
Tanner, DB
MacDiarmid, AG
Reynolds, JR
[J]. CHEMISTRY OF MATERIALS, 2004, 16 (23) : 4401 - 4412
[5] All jet-printed polymer thin-film transistor active-matrix backplanes
Arias, AC
Ready, SE
Lujan, R
Wong, WS
Paul, KE
Salleo, A
Chabinyc, ML
Apte, R
Street, RA
Wu, Y
Liu, P
Ong, B
[J]. APPLIED PHYSICS LETTERS, 2004, 85 (15) : 3304 - 3306
[6] Long-lived solid state perchlorate ion selective sensor based on doped poly(3,4-ethylenedioxythiophene) (PEDOT) films
Bendikov, TA
Harmon, TC
[J]. ANALYTICA CHIMICA ACTA, 2005, 551 (1-2) : 30 - 36
[7] Bhushan B., 1995, HDB MICRO NANOTRIBOL
[8] Synthesis of highly conductive EDOT copolymer films via oxidative chemical in situ polymerization
Chen, Jui Hung
Dai, Chi-An
Chiu, Wen-Yen
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (05) : 1662 - 1673
[9] Spectroscopic and conductivity studies of doping in chemically synthesized poly(3,4-ethylenedioxythiophene)
Chiu, WW
Travas-Sejdic, J
Cooney, RP
Bowmaker, GA
[J]. SYNTHETIC METALS, 2005, 155 (01) : 80 - 88
[10] Electrochemical synthesis of poly(3,4-ethylenedioxythiophene) nanotubes towards fast window-type electrochromic devices
Cho, Seung Il
Xiao, Rui
Lee, Sang Bok
[J]. NANOTECHNOLOGY, 2007, 18 (40)

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