Chloro(methyl)(η5-pentamethylcyclopentadienyl)(trimethylphosphine)rhodium(III)

被引：1

作者：

Wendt, OF ^{[1
]}

机构：

[1] Lund Univ, Dept Chem, S-22100 Lund, Sweden

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801016798

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, RhCp*Me(Cl)(PMe3) or [RhCl(CH3)-(C10H15)(C3H9P)], where Cp* is pentamethylcyclopentadienyl, has a pseudo-tetrahedral coordination geometry. The Cp* ligand is planar and eta (5)-coordinated. The molecular structure can be described as a so-called three-legged piano-stool. The rhodium-methyl, rhodium-chlorine and rhodium-phosphorus distances are 2.255 (4), 2.3764 (18) and 2.2436 (13) Angstrom, respectively.

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页码：M517 / M518

页数：2

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