Waste to MOFs: sustainable linker, metal, and solvent sources for value-added MOF synthesis and applications

被引：151

作者：

El-Sayed, El-Sayed M. ^{[1
,2
,3
]}

Yuan, Daqiang ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China

[2] Univ Chinese Acad Sci, Beijing, Peoples R China

[3] Egyptian Petr Res Inst, Refining Dept, Chem Refining Lab, Cairo, Egypt

来源：

GREEN CHEMISTRY | 2020年 / 22卷 / 13期

基金：

中国国家自然科学基金;

关键词：

POLYETHYLENE TEREPHTHALATE WASTES; ROOM-TEMPERATURE SYNTHESIS; ORGANIC FRAMEWORK UIO-66; HIGH CO/CO2 SELECTIVITY; CARBON-BLACK WASTE; POLY(ETHYLENE NAPHTHALATE); PET BOTTLES; DIHYDROLEVOGLUCOSENONE CYRENE; ADSORPTION PROPERTIES; COORDINATION POLYMER;

D O I：

10.1039/d0gc00353k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Greening of the synthetic route for metal-organic frameworks (MOFs) has attracted much interest as a decisive step for practical industrial applications. For a more feasible process, employing waste plastic materials as a potential linker source for MOF synthesis is highly encouraging, combining a sustainable and environmentally friendly approach for scale-up production. The process is more economical when the whole MOF synthesis can be achieved based on waste metal and linker sources in the presence of green solvents derived from waste materials as well. Herein, we present a waste valorization approach for the preparation of MOFs based on different recycled polymer waste materials, MOFs based on waste metal sources, and MOFs based on the coupling of waste sources for both the organic ligand and metal center. This approach not only recycles discarded products but also produces high value-added costly materials for different applications.

引用

页码：4082 / 4104

页数：23

共 157 条

[1] Nanosize Zr-metal organic framework (UiO-66) for hydrogen and carbon dioxide storage [J].