Shape-size sieving of trans- and cis-piperylene isomers with gallate-based metal-organic frameworks

被引：2
作者：
Chen, Jie [1 ]
Wang, Jiawei [1 ,2 ]
Guo, Lidong [1 ]
Liu, Ying [1 ]
Yang, Qiwei [1 ,3 ]
Zhang, Zhiguo [1 ,3 ]
Yang, Yiwen [1 ,3 ]
Bao, Zongbi [1 ,3 ]
Ren, Qilong [1 ,3 ]
机构：
[1] Zhejiang Univ, Key Lab Biomass Chem Engn, Minist Educ, Coll Chem & Biol Engn, Hangzhou 310027, Peoples R China
[2] Hangzhou Oxygen Plant Grp Co Ltd, Hangzhou, Peoples R China
[3] Inst Zhejiang Univ Quzhou, Res Inst Elect Chem, Quzhou, Peoples R China
来源：
AICHE JOURNAL | 2022年 / 68卷 / 07期
基金：
中国国家自然科学基金;
关键词：
C-5; diolefins; geometric isomers; metal-organic frameworks; M-gallate; shape-size sieving; CATIONIC-POLYMERIZATION; 1,3-PENTADIENE; ADSORPTION; COPOLYMERIZATION; SEPARATION; ETHYLENE; LIQUID;
D O I：
10.1002/aic.17671
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The isolation of C-5 diolefins, mainly consisting of trans-piperylene, cis-piperylene, and isoprene, is a challenging task and requires complex and energy-intensive separation schemes. Particularly, the segregation of trans/cis-piperylene is the most challenging operation for geometric isomers. Here, we report an isostructural family of metal-organic frameworks, Mg-, Co-, and Ni-gallate, which are perfectly suitable for the precise matching of trans-piperylene molecules while excluding the slightly large cis-piperylene molecules, contributing to remarkable separation of trans/cis-piperylene via shape-size sieving. Significantly, Mg-gallate exhibits high affinity for trans-piperylene, leading to an outstanding trans/cis-piperylene uptake selectivity of 4.22 (298 K, 0.1 bar) in adsorption isotherms. This excellent separation performance is further attested by single-crystal x-ray diffraction of Ni-gallate loaded with trans-piperylene isomer. In breakthrough tests, M-gallate materials not only display excellent separation performance of trans- and cis-piperylene but also can accomplish complete segregation of the ternary mixture (trans-piperylene/cis-piperylene/isoprene) into individual compounds combined with zeolite 5A.
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页数：9
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