Asymmetric catalysis with bifunctional cinchona alkaloid-based urea and thiourea organocatalysts

被引：777
作者：
Connon, Stephen J. [1 ]
机构：
[1] Univ Dublin, Ctr Synth & Chem Biol, Sch Chem, Trinity Coll, Dublin 2, Ireland
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 22期
关键词：
D O I：
10.1039/b719249e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cinchona alkaloid derivatives modified to include a (thio) urea component have emerged in the last three years as readily accessible, robust and tunable bifunctional organocatalysts for a range of synthetically useful transformations. The origins of these catalysts and the major developments in their application in enantioselective synthesis are reviewed.
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页码：2499 / 2510
页数：12
相关论文
共 127 条
[1]   Recent progress in chiral Bronsted acid catalysis [J].
Akiyama, Takahiko ;
Itoh, Junji ;
Fuchibe, Kohei .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (09) :999-1010
[2]   Organocatalytic asymmetric conjugate additions [J].
Almasi, Diana ;
Alonso, Diego A. ;
Najera, Carmen .
TETRAHEDRON-ASYMMETRY, 2007, 18 (03) :299-365
[3]   Highly enantioselective decarboxylative protonation of α-aminomalonates mediated by thiourea Cinchona alkaloid derivatives:: Access to both enantiomers of cyclic and acyclic α-aminoacids [J].
Amere, Mukkanti ;
Lasne, Marie-Claire ;
Rouden, Jacques .
ORGANIC LETTERS, 2007, 9 (14) :2621-2624
[4]   CONJUGATED NITROALKENES - VERSATILE INTERMEDIATES IN ORGANIC-SYNTHESIS [J].
BARRETT, AGM ;
GRABOSKI, GG .
CHEMICAL REVIEWS, 1986, 86 (05) :751-762
[5]   Organocatalytic asymmetric hydrophosphination of nitroalkenes [J].
Bartoli, Giuseppe ;
Bosco, Marcella ;
Carlone, Armando ;
Locatelli, Manuela ;
Mazzanti, Andrea ;
Sambri, Letizia ;
Melchiorre, Paolo .
CHEMICAL COMMUNICATIONS, 2007, (07) :722-724
[6]   Organocatalytic asymmetric conjugate addition of 1,3-dicarbonyl compounds to maleimides [J].
Bartoli, Giuseppe ;
Bosco, Marcella ;
Carlone, Armando ;
Cavalli, Andrea ;
Locatelli, Manuela ;
Mazzanti, Andrea ;
Ricci, Paolo ;
Sambri, Letizia ;
Melchiorre, Paolo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (30) :4966-4970
[7]  
Berkessel A, 2005, ASYMMETRIC ORGANOCATALYSIS: FROM BIOMIMETIC CONCEPTS TO APPLICATIONS IN ASYMMETRIC SYNTHESIS, P1, DOI 10.1002/3527604677
[8]   Improved synthesis of both enantiomers of trans-cyclohex-4-ene-1,2-dicarboxylic acid [J].
Bernardi, A ;
Arosio, D ;
Dellavecchia, D ;
Micheli, F .
TETRAHEDRON-ASYMMETRY, 1999, 10 (17) :3403-3407
[9]   Enantioselective aza-Henry reaction using cinchona organocatalysts [J].
Bernardi, L ;
Fini, F ;
Herrera, RP ;
Ricci, A ;
Sgarzani, V .
TETRAHEDRON, 2006, 62 (2-3) :375-380
[10]  
Berner OM, 2002, EUR J ORG CHEM, V2002, P1877
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