Two-photon and three-photon absorption in dinaphthoporphycenes

被引：69

作者：

Rao, S. Venugopal ^{[1
]}

Prashant, T. Shuvan ^{[1
]}

Swain, Debasis ^{[1
]}

Sarma, Tridib ^{[2
]}

Panda, Pradeepta K. ^{[1
,2
]}

Tewari, Surya P. ^{[1
]}

机构：

[1] Univ Hyderabad, ACRHEM, Hyderabad 500046, Andhra Pradesh, India

[2] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

CHEMICAL PHYSICS LETTERS | 2011年 / 514卷 / 1-3期

关键词：

NONLINEAR-OPTICAL PROPERTIES; Z-SCAN TECHNIQUE; CROSS-SECTIONS; EXPANDED PORPHYRINS; PHTHALOCYANINES; CHROMOPHORES; FEMTOSECOND; PORPHYCENES; AROMATICITY; DERIVATIVES;

D O I：

10.1016/j.cplett.2011.08.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present our results from the detailed investigations of both metal free-base and metal substituted dinaphthoporphycenes using the Z-scan technique with picosecond pulses. The compounds exhibited singular nonlinear absorption properties because of their molecular structure allowing us to access the two-photon and three-photon absorption states with different peak intensities when excited at the wavelength of 800 nm. This type of behaviour is explained using the unique energy level configuration of porphycene molecules. The orders of magnitude of both two-photon absorption and effective three-photon absorption coefficients and cross-sections were estimated along with sign and magnitude of the third order nonlinearity. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：98 / 103

页数：6

共 47 条

[1] Design of organic molecules with large two-photon absorption cross sections [J].

Albota, M ;

Beljonne, D ;

Brédas, JL ;

Ehrlich, JE ;

Fu, JY ;

Heikal, AA ;

Hess, SE ;

Kogej, T ;

Levin, MD ;

Marder, SR ;

McCord-Maughon, D ;

Perry, JW ;

Röckel, H ;

Rumi, M ;

Subramaniam, C ;

Webb, WW ;

Wu, XL ;

Xu, C .

SCIENCE, 1998, 281 (5383) :1653-1656

[2] Two-photon absorption investigation in reduced and oxidized cytochrome c solutions [J].

Andrade, AA ;

Neto, NMB ;

Misoguti, L ;

De Boni, L ;

Zilio, SC ;

Mendonça, CR .

CHEMICAL PHYSICS LETTERS, 2004, 390 (4-6) :506-510

[3] Optical limiting in the visible range:: molecular engineering around N4,N4′-bis(4-methoxyphenyl)-N4,N4′-diphenyl-4,4′-diaminobiphenyl [J].

Anémian, R ;

Morel, Y ;

Baldeck, PL ;

Paci, B ;

Kretsch, K ;

Nunzi, JM ;

Andraud, C .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (09) :2157-2163

[4] Diethyl 2,7-dibromo-4H,5H-thieno[3,2-b:4,5-b′]dipyrrole-3,6-dicarboxylate:: A key intermediate for a diversity oriented synthesis of 2,7,12,17-tetraarylporphycenes [J].

Arad, O ;

Morros, J ;

Batllori, X ;

Teixidó, J ;

Nonell, S ;

Borrell, JI .

ORGANIC LETTERS, 2006, 8 (05) :847-850

[5] Two-photon absorption in tetraphenylporphycenes:: Are porphycenes better candidates than porphyrins for providing optimal optical properties for two-photon photodynamic therapy? [J].

Arnbjerg, Jacob ;

Jimenez-Banzo, Ana ;

Paterson, Martin J. ;

Nonell, Santi ;

Borrell, Jose I. ;

Christiansen, Ove ;

Ogilby, Peter R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (16) :5188-5199

[6]

Belfield KD, 2000, J PHYS ORG CHEM, V13, P837, DOI 10.1002/1099-1395(200012)13:12<837::AID-POC315>3.0.CO

[7]

2-5

[8] NONDEGENERATE MULTIWAVE MIXING IN POLYDIACETYLENE - PHASE CONJUGATION WITH FREQUENCY-CONVERSION [J].

CHARRA, F ;

NUNZI, JM .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1991, 8 (03) :570-577

[9] Study on Z-scan characteristics for a large nonlinear phase shift [J].

Chen, SQ ;

Liu, ZB ;

Zang, WP ;

Tian, JG ;

Zhou, WY ;

Song, F ;

Zhang, CP .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2005, 22 (09) :1911-1916

[10] Metalloporphycenes: Synthesis and Characterization of (Pentamethylcyclopentadienyl)ruthenium Sitting-Atop and π-Complexes [J].

Cuesta, Luciano ;

Karnas, Elizabeth ;

Lynch, Vincent M. ;

Chen, Ping ;

Shen, Jing ;

Kadish, Karl M. ;

Ohkubo, Kei ;

Fukuzumi, Shunichi ;

Sessler, Jonathan L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (37) :13538-13547

← 1 2 3 4 5 →