A New 3-D Open-Framework Zinc Borovanadate with Catalytic Potentials in α-Phenethyl Alcohol Oxidation

被引：8

作者：

Liu, Xinxin ^{[1
,2
]}

Guo, Biao ^{[2
]}

Sun, Xuejiao ^{[1
]}

Zhang, Le ^{[1
]}

Yuan, Hongming ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

[2] Shenyang Normal Univ, Coll Chem & Chem Engn, Inst Catalysis Energy & Environm, Shenyang 110034, Liaoning, Peoples R China

来源：

MOLECULES | 2019年 / 24卷 / 03期

关键词：

borovanadate; open framework; three-dimensional; catalytic activities; GROUP OXIDE CLUSTER; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; II COMPLEXES; CU-II; VANADOBORATE; ARYLHYDRAZONES; LATTICE; OXYGEN;

D O I：

10.3390/molecules24030531

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A novel 3-D open-framework zinc borovanadate [Zn-6(en)(3)][((VO)-O-IV)(6)((VO)-O-V)(6)O-6(B18O36(OH)(6))(H2O)](2)center dot 14H(2)O (1, en = ethylenediamine) was hydrothermally obtained and structurally characterized. The framework was built from [V12B18O54(OH)(6)(H2O)](10-) polyanion clusters bridged by Zn(en) complex fragments. The compound not only possessed a three-dimensional open-framework structure with unique plane-shaped channels, but also exhibited excellent catalytic activities for the oxidation of alpha-phenethyl alcohol.

引用

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