Synthesis and dielectric and ferroelectric properties of ceramics in (1-x)Pb(Zr1/2Ti1/2)O3-(x)Pb(Co1/3Nb2/3)O3 system

被引:24
作者
Prasatkhetragarn, Anurak [1 ]
Vittayakorn, Naratip [2 ]
Ananta, Supon [1 ]
Yimnirun, Rattikorn [1 ]
Cann, David P. [3 ]
机构
[1] Chiang Mai Univ, Fac Sci, Dept Phys, Chiang Mai 50200, Thailand
[2] King Mongkuts Inst Technol Ladkrabang, Fac Sci, Dept Chem, Bangkok 10520, Thailand
[3] Oregon State Univ, Dept Mech Engn, Corvallis, OR 97331 USA
关键词
ferroelectric properties; perovskites; MPB; phase transition;
D O I
10.1143/JJAP.47.998
中图分类号
O59 [应用物理学];
学科分类号
摘要
Ceramics in a PZT-PCN system with the formula (1 - x)Pb(Zr1/2Ti1/2)O-3-(x)Pb(Co1/3Nb2/3)O-3, where x = 0.1-0.5, were prepared using a solid-state mixed-oxide technique (the columbite-wolframite precursor method). The phase formation behavior and microstructure were studied using X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM), respectively. The dielectric and ferroelectric properties of the compounds were studied and discussed. Phase-pure perovskites of PZT-PCN ceramics were obtained over a wide compositional range. In addition, the XRD, dielectric, and ferroelectric properties confirmed that the morphotropic phase boundary (MPB) composition between the tetragonal and pseudo cubic phases of this system lied between 0.2 <= x <= 0.3.
引用
收藏
页码:998 / 1002
页数:5
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