An unprecedented 1-D mixed-valence Cu(II)/Cu(I) metal-organic framework bearing 2-phenyl imidazole dicarboxylates

被引：47

作者：

Zhu, Yu ^{[1
]}

Wang, Wen-yue ^{[1
]}

Guo, Meng-wei ^{[1
]}

Li, Gang ^{[1
]}

Lu, Hui-jie ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Mixed-valence; Copper; Polymer; Phenyl imidazole dicarboxylate; Crystal structure; 2D COORDINATION POLYMER; CRYSTAL-STRUCTURE; LUMINESCENT PROPERTY; IMIDAZOLE-4,5-DICARBOXYLATE; COMPLEXES; WATER; LIGANDS; CD(II); 1H-IMIDAZOLE-4,5-DICARBOXYLATE; CONSTRUCTION;

D O I：

10.1016/j.inoche.2011.05.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unprecedented mixed-valence Cu(I)/Cu(II) metal-organic framework {[Cu-2(HPhIDC)(OH)]center dot H2O}(n) (H3PhIDC=2-phenyl-1H-imidazole-4,5-dicarboxylic acid) (1) has been solvothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, XPS spectrum and single crystal X-ray diffraction analysis. In 1, each Cu(I) ion is two-coordinated by imidazole and OH(-)units. The HPhIDC(2-)ligands connect Cu(II) ions leading to a one-dimensional chain structure. The thermal properties of 1 are reported. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1432 / 1435

页数：4

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