Highly efficient colloidal MnxCd1-xS nanorod solid solution for photocatalytic hydrogen generation

被引：78

作者：

Li, Ling ^{[1
]}

Liu, Guoning ^{[1
]}

Qi, Shaopeng ^{[1
]}

Liu, Xindi ^{[1
]}

Gu, Liuyu ^{[1
]}

Lou, Yongbing ^{[1
]}

Chen, Jinxi ^{[1
]}

Zhao, Yixin ^{[2
]}

机构：

[1] Southeast Univ, Jiangsu Key Lab Sci & Applicat Mol Ferroelect, Jiangsu Engn Lab Smart Carbon Rich Mat & Device, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

[2] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2018年 / 6卷 / 46期

基金：

中国国家自然科学基金;

关键词：

LIGHT-DRIVEN PHOTOCATALYST; MN-CD-S; VISIBLE-LIGHT; H-2; EVOLUTION; HYDROTHERMAL SYNTHESIS; WATER; NANOWIRES; COMPOSITE;

D O I：

10.1039/c8ta08458k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, a series of MnxCd1-xS nanorods solid solutions featuring precisely controlled band gap and suitable conduction band position were fabricated for the first time with a hot-injection synthesis under N-2 atmosphere. Correspondingly, the colloidal Mn0.5Cd0.5S solid solution exhibited the highest photocatalytic H-2 generation rate of 26000 mol g(-1) h(-1) and the apparent quantum efficiency of 30.3% at 400 nm, which is approximately 216 times higher than that of pristine h-CdS and 565 times higher than that of -MnS alone. Moreover, the MnxCd1-xS solid solution showed good photocatalytic stability because of a proper conduction band position and high crystallinity. This work demonstrates that this hot-injection strategy for developing highly efficient MnxCd1-xS solid solution is promising for preparing other binary or multicomponent solid solutions for a variety of photocatalytic applications.

引用

页码：23683 / 23689

页数：7

共 42 条

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