anti-Markovnikov acetoxyphenylselenation of terminal alkenes

被引：0

作者：

Vukievic, RD ^{[1
]}

Radovic, M ^{[1
]}

机构：

[1] Univ Kragujevac, Fac Sci, Dept Chem, YU-34000 Kragujevac, FR, Yugoslavia

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2001年 / 40卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unexpected anti-Markovnikov acetoxyphenylselenation of terminal alkenes has been achieved by reaction of these. substrates with diphenyl diselenide and lead tetraacetate in benzene under thermal conditions (80 degreesC). The corresponding products, 1-acetoxy-2-phenylselenylhydrocarbons accompanied by their isomers, 2-acetoxy-1-phenylselenilhydrocarbons are obtained in moderate to good yields. Acetoxyphenylselenation with same reagents, but in acetic acid as the solvent, yields only expected Markovnikov products.

引用

页码：470 / 474

页数：5

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