Copper(II) Acetate-Catalyzed Synthesis of Phosphorylated Pyridines via Denitrogenative C-P Coupling between Pyridotriazoles and P(O)H Compounds

被引：33

作者：

Shen, Ruwei ^{[1
]}

Dong, Chao ^{[1
]}

Yang, Jianlin ^{[1
]}

Han, Li-Biao ^{[2
]}

机构：

[1] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 21期

关键词：

Copper catalysis; Pyridotriazoles; C-P coupling; 2-Picolylphosphoryl compounds; LANTHANIDE COORDINATION CHEMISTRY; ONE-POT SYNTHESIS; TRANSANNULATION REACTION; N-TOSYLHYDRAZONES; LIGANDS; ALKYNES; TRIAZOLOPYRIDINES; PHOSPHONATES; HETEROCYCLES; CYCLIZATION;

D O I：

10.1002/adsc.201800909

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new inexpensive copper-catalyzed denitrogenative C-P coupling reaction of pyridotriazoles with P(O)H compounds has been developed. The reaction proceeds via a process of copper-catalyzed P(O)-H insertion into the pyridyl carbene intermediates generated in situ from pyridotriazoles. This reaction provides a new and effective method for the synthesis of a variety of 2-picolylphosphoryl compounds.

引用

页码：4252 / 4258

页数：7

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