Electrochemical and photocatalytic properties of WO3 coatings grown at low temperatures

被引：66
作者：
Vernardou, D. [1 ,2 ,3 ]
Drosos, H. [4 ]
Spanakis, E. [2 ,3 ,6 ]
Koudoumas, E. [1 ,5 ]
Savvakis, C. [1 ,2 ]
Katsarakis, N. [1 ,2 ,6 ]
机构：
[1] Technol Educ Inst Crete, Sch Appl Technol, Ctr Mat Technol & Photon, Iraklion 71004, Crete, Greece
[2] Technol Educ Inst Crete, Sch Appl Technol, Dept Sci, Iraklion 71004, Crete, Greece
[3] Univ Crete, Dept Mat Sci & Technol, Iraklion 71003, Crete, Greece
[4] Technol Educ Inst Crete, Sch Appl Technol, Dept Mech Engn, Iraklion 71004, Crete, Greece
[5] Technol Educ Inst Crete, Sch Appl Technol, Dept Elect Engn, Iraklion 71004, Crete, Greece
[6] Fdn Res & Technol Hellas, Inst Elect Struct & Laser, Iraklion 71110, Crete, Greece
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 02期
关键词：
OXIDE THIN-FILMS; TUNGSTEN-OXIDE; HYDROTHERMAL SYNTHESIS; ELECTROCHROMIC PROPERTIES; TIO2; DEPOSITION; NANOWIRES;
D O I：
10.1039/c0jm02413a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The growth of tungsten oxide was carried out on microscope glass substrates using the one-pot direct hydrothermal method. Despite the simplicity of the technique, the coating grown using 0.3 M NaOH at 95 degrees C after 30 h, exhibited reversible electrochemical response without significant degradation, as studied by cycling voltammetry experiments for at least 250 times in a solution of 1 M LiClO4. This coating at the same time presented marked photocatalytic activity under solar illumination, degrading stearic acid by 52%. The results are discussed in terms of the materials' observed morphology towards which, the role of the growth solution chemistry is examined.
引用
收藏
页码：513 / 517
页数：5
相关论文
共 29 条
  • [1] [Anonymous], 2008, ANGEW CHEM, DOI [DOI 10.1002/ANGE.200802207, DOI 10.1002/ange.200802207]
  • [2] Crystallite nanosize effect on the structural transitions of WO3 studied by Raman spectroscopy
    Boulova, M
    Lucazeau, G
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2002, 167 (02) : 425 - 434
  • [3] Roll-to-roll pulsed dc magnetron sputtering deposition of WO3 for electrochromic windows
    Brigouleix, C
    Topart, P
    Bruneton, E
    Sabary, F
    Nouhaut, G
    Campet, G
    [J]. ELECTROCHIMICA ACTA, 2001, 46 (13-14) : 1931 - 1936
  • [4] THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS
    CHOI, WY
    TERMIN, A
    HOFFMANN, MR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) : 13669 - 13679
  • [5] HETEROGENEOUS PHOTOCATALYSIS
    FOX, MA
    DULAY, MT
    [J]. CHEMICAL REVIEWS, 1993, 93 (01) : 341 - 357
  • [6] Large-scale synthesis of single-crystal hexagonal tungsten trioxide nanowires and electrochemical lithium intercalation into the nanocrystals
    Gu, Zhanjun
    Li, Huiqiao
    Zhai, Tianyou
    Yang, Wensheng
    Xia, Yongyao
    Ma, Ying
    Yao, Jiannian
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (01) : 98 - 105
  • [7] Controllable assembly of WO3 nanorods/nanowires into hierarchical nanostructures
    Gu, Zhanjun
    Zhai, Tianyou
    Gao, Bifen
    Sheng, Xiaohai
    Wang, Yaobing
    Fu, Hongbing
    Ma, Ying
    Yao, Jiannian
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (47) : 23829 - 23836
  • [8] Hydrothermal synthesis and characterization of self-assembled h-WO3 nanowires/nanorods using EDTA salts
    Ha, Jang-Hoon
    Muralidharan, P.
    Kim, Do Kyung
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 475 (1-2) : 446 - 451
  • [9] Characterization of electrodeposited WO3 films and its application to electrochemical wastewater treatment
    Habazaki, H
    Hayashi, Y
    Konno, H
    [J]. ELECTROCHIMICA ACTA, 2002, 47 (26) : 4181 - 4188
  • [10] Controllable synthesis of hexagonal WO3 nanostructures and their application in lithium batteries
    Huang, Kai
    Pan, Qingtao
    Yang, Feng
    Ni, Shibing
    Wei, Xiucheng
    He, Deyan
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2008, 41 (15)
123