S,O or S,N Coordination? Unraveling the Coordination Modes of Arenesulfonylthiourea Ligands

被引：4
作者：
Beele, Bjoern B. [1 ]
Bill, Eckhard [2 ]
Mohr, Fabian [1 ]
机构：
[1] Berg Univ Wuppertal, Anorgan Chem, Fak Math & Nat Wissensch, D-42119 Wuppertal, Germany
[2] Max Planck Inst Chem Energiekonvers, D-45470 Mulheim, Germany
来源：
CRYSTAL GROWTH & DESIGN | 2022年 / 22卷 / 05期
关键词：
HEXANUCLEAR COPPER(I) COMPLEXES; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; LUMINESCENCE PROPERTY; SILVER(I) CLUSTER; THIOUREA; BENZOYLTHIOUREA; DERIVATIVES; EXTRACTION; IONS;
D O I：
10.1021/acs.cgd.2c00231
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two arenesulfonylthioureas were prepared and reacted with a variety of transition-metal salts, including Ni(OAc)2, Co(OAc)2, Cu(OAc)2, CuCl2, AgNO3, and Zn(OAc)2. In all cases, complexes containing the arenesulfonylthioureas acting as monoanionic [S,N]-chelating ligands were isolated and characterized by X-ray diffraction, NMR spectroscopy, and magnetic measurements. Copper(I) and silver(I) complexes exist as hexanuclear [M6L6] clusters, which are luminescent in the solid state and solution.
引用
收藏
页码：3442 / 3456
页数：15
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