Effect of Sensitization on Pitting Corrosion at MnS and CrS in Type 304 Stainless Steel

被引：16

作者：

Tokuda, Shimpei ^{[1
]}

Muto, Izumi ^{[1
]}

Sugawara, Yu ^{[1
]}

Hara, Nobuyoshi ^{[1
]}

机构：

[1] Tohoku Univ, Dept Mat Sci, Sendai, Miyagi 9808579, Japan

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2021年 / 168卷 / 09期

关键词：

Pitting; Stainless steel; Sensitization; Sulfide inclusion; SINGLE SULFIDE INCLUSIONS; STAINLESS-STEEL; PIT INITIATION; MICROELECTROCHEMICAL MEASUREMENTS; INTERGRANULAR CORROSION; CREVICE CORROSION; BEHAVIOR; MECHANISM; SULFUR; PH;

D O I：

10.1149/1945-7111/ac28c6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The effect of sensitization on the pitting potentials at MnS and CrS inclusions in Type 304 stainless steels was assessed. For Type 304 containing MnS inclusions, MnS dissolution was observed approximately 0.3 V, and the pitting potential at MnS was in the passive region and decreased by sensitization. Based on the pit morphology, the pit initiation at MnS inclusions is thought to be caused by the transition from passive to active state of the steel matrix. In contrast, the pitting potential at CrS inclusions was located in the transpassive region, and no decrease in the pitting potential was observed due to sensitization. These mechanisms were analyzed based on the effect of the Cr concentration on the active dissolution and transpassive dissolution of the steel.

引用

页数：8

共 48 条

[41] The role of applied stress in the anodic dissolution of sulfide inclusions and pit initiation of stainless steels [J].