Physics of polymer melts

被引:0
|
作者
Chitanvis, SM [1 ]
机构
[1] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA
来源
PHYSICAL REVIEW E | 2001年 / 63卷 / 02期
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暂无
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We have mapped the physics of polymer melts onto a time-dependent Landau-Ginzburg \psi\(4) field theory using techniques of functional integration. Time in the theory is simply a label fur the location of a given monomer along the extent of a flexible chain. With this model, one can show that the limit of infinitesimal concentration of a polymer melt corresponds to a dynamic critical phenomenon. The transition to the entangled stare is also shown to be a critical point. For larger concentrations, when the role of fluctuations is reduced, a mean-held approximation is justifiably employed to show the existence of tubelike structures reminiscent of Edwards' model.
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页数:6
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