Direct C(sp3)-O reductive elimination of olefin oxides from PtIV-oxetanes prepared by aerobic oxidation of PtII olefin derivatives (Olefin = cis-cyclooctene, norbornene)

被引：70

作者：

Khusnutdinova, Julia R. ^{[1
]}

Newman, Laura L. ^{[1
]}

Zavalij, Peter Y. ^{[1
]}

Lam, Yiu-Fai ^{[1
]}

Vedernikov, Andrei N. ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 07期

关键词：

D O I：

10.1021/ja7107323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Internal olefins, cis-cyclooctene and norbornene, react with (dpms)Pt-II(OH)(ethene) in water to produce Pt-II oxetanes (norbornene) or hydroxo olefin complexes (cis-cyclooctene); both produce anionic Pt-II oxetanes in basic solutions; their subsequent aerobic oxidation cleanly furnishes corresponding Pt-II oxetanes that undergo direct C(sp(3))-O reductive elimination of olefin oxides in various solvents and in the solid-state that is unprecedented for Pt-IV.

引用

页码：2174 / +

页数：3

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