Gold-catalyzed intermolecular hydroamination of allenes: First example of the use of an aliphatic amine in hydroamination

被引：74

作者：

Nishina, Naoko ^{[1
]}

Yamamoto, Yoshinori ^{[1
]}

机构：

[1] Tohoku Univ, Fac Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

SYNLETT | 2007年 / 11期

关键词：

hydroamination; gold catalyst; aliphatic amine; allenes; gold-phosphine complex;

D O I：

10.1055/s-2007-984501

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of allenes with morpholine in the presence of cationic gold(I) catalyst ill toluene at 80 degrees C gave the corresponding allylic airlines in good to moderate yields. To the best of our knowledge. this is the first example for carrying out the gold-catalyzed intermolecular hydroamination with an aliphatic amine.

引用

页码：1767 / 1770

页数：4

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