Bis{(E)-1-[1-(2-pyridyl)ethylidene]thio-semicarbazonato-κ3N,N′,S}gallium(III)nitrate

被引：1

作者：

Fan, Ying-Ju ^{[1
]}

Ma, Jian-Ping

Sun, Zhong-Xi

机构：

[1] Jinan Univ, Sch Chem & Chem Engn, Jinan 250022, Peoples R China

[2] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S160053680704799X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Reaction of gallium(III) nitrate with (E)-1-[1-(2-pyridyl)ethylidene] thiosemicarbazide (petc) afforded the title complex, [Ga(C8H9N4S)(2)]NO3. The title complex contains one Ga-III cation and two enol-form petc anions, accompanied by one charge-balancing disordered nitrate anion. The petc is in the enol form, coordinating to the Ga-III centre via one S atom and two N atoms. Thus, the Ga-III centre assumes a distorted octahedral coordination geometry.

引用

页码：M2663 / U337

页数：10

共 5 条

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