Facile Synthesis of Copper-Based Metal Oxide Nanoparticles with Exceptional Catalytic Activity for the Selective Oxidation of Styrenes into Benzaldehydes

被引：10

作者：

Ge, Danhua ^{[1
,2
]}

Wang, Jiaqing ^{[1
,2
]}

Geng, Hongbo ^{[1
,2
]}

Lu, Shuanglong ^{[1
,2
]}

Wang, Dongtao ^{[1
,2
]}

Li, Xinming ^{[1
,2
]}

Zhao, Xianli ^{[3
]}

Cao, Xueqin ^{[1
,2
]}

Gu, Hongwei ^{[1
,2
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

[2] Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215123, Peoples R China

[3] Jiangsu Sunshine Co Ltd, Jiangyin 214426, Peoples R China

来源：

CHEMPLUSCHEM | 2015年 / 80卷 / 03期

基金：

中国国家自然科学基金;

关键词：

copper; nanoparticles; oxidation; self-assembly; styrene; SCHIFF-BASE; DERIVATIVES; COMPLEXES; POLYMER; H2O2;

D O I：

10.1002/cplu.201402319

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of highly efficient catalysts for the selective oxidation of styrene to benzaldehyde has attracted great attention in recent years because of its significance in synthetic chemistry. In this study, two different kinds of copper-based metal oxide nanoparticles (NPs), namely, CuO and CuO/Co3O4 NPs, were synthesized by a simple and scalable method, and these nanoparticles demonstrated efficient catalytic abilities for the selective oxidation of styrene and its derivatives to the corresponding aldehydes in the presence of tert-butyl hydroperoxide (TBHP) under mild reaction conditions in excellent yields. Importantly, both of the heterogeneous catalysts can be recycled up to five runs while still maintaining their high catalytic activity.

引用

页码：511 / 515

页数：5

共 19 条

[1] A reusable CuII based metal-organic framework as a catalyst for the oxidation of olefins [J].

Cancino, Patricio ;

Paredes-Garcia, Veronica ;

Aguirre, Pedro ;

Spodine, Evgenia .

CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (08) :2599-2607

[2] CONVENIENT SYNTHESIS OF NOVEL NITRONES: (Z)-4-AMINO-5-(HYDROXYIMINO)-2,5-DIHYDRO-1H-IMIDAZOLE 3-OXIDES [J].

Cao, Xue-Qin ;

Li, Zhan-Xiong ;

Zhong, Wen-Xing ;

Qiu, Li-Hua ;

Chen, Guo-Qiang .

HETEROCYCLES, 2009, 78 (06) :1445-1452

[3] Supported Gold Nanoparticles Catalysts for Solvent-free Selective Oxidation of Benzylic Compounds into Ketones at 1 atm O2 [J].

Dapurkar, Sudhir E. ;

Shervani, Zameer ;

Yokoyama, Toshirou ;

Ikushima, Yutaka ;

Kawanami, Hajime .

CATALYSIS LETTERS, 2009, 130 (1-2) :42-47

[4] Preparation of Pt@Fe2O3 Nanowires and their Catalysis of Selective Oxidation of Olefins and Alcohols [J].

Hong, Haiyan ;

Hu, Lei ;

Li, Min ;

Zheng, Junwei ;

Sun, Xuhui ;

Lu, Xinhua ;

Cao, Xueqin ;

Lu, Jianmei ;

Gu, Hongwei .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (31) :8726-8730

[5] Oxidation of benzylic compounds by gold nanowires at 1 atm O2 [J].

Hu, Lei ;

Cao, Xueqin ;

Yang, Jianhui ;

Li, Min ;

Hong, Haiyan ;

Xu, Qingfeng ;

Ge, Jianfeng ;

Wang, Lihua ;

Lu, Jianmei ;

Chen, Liang ;

Gu, Hongwei .

CHEMICAL COMMUNICATIONS, 2011, 47 (04) :1303-1305

[6] Styrene oxidation with H2O2 over Ti-containing molecular sieves with MFI, BEA and MCM-41 topologies [J].

Hulea, V ;

Dumitriu, E .

APPLIED CATALYSIS A-GENERAL, 2004, 277 (1-2) :99-106

[7] A New Copper(I) Coordination Polymer with N2-Donor Schiff Base and Its Use as Precursor for CuO Nanoparticle: Spectroscopic, Thermal and Structural Studies [J].

Khalaji, Aliakbar Dehno ;

Rohlicek, Jan ;

Machek, Pavel ;

Das, Debasis .

JOURNAL OF CLUSTER SCIENCE, 2014, 25 (05) :1425-1434

[8] Enhanced Aerobic Epoxidation of Styrene with Copper(II), Cobalt(II), Iron(III), or Oxovanadium(IV) Salen Complexes Immobilized onto Carbon-Coated Fe3O4 Nanoparticles Hybridized with Graphene Sheets [J].

Li, Zhifang ;

Wu, Shujie ;

Zheng, Dafang ;

Ding, Hong ;

Wang, Xiufang ;

Yang, Xiaoyuan ;

Huo, Qisheng ;

Guan, Jingqi ;

Kan, Qiubin .

CHEMPLUSCHEM, 2014, 79 (05) :716-724

[9] One-pot synthesis of CuO nanoflower-decorated reduced graphene oxide and its application to photocatalytic degradation of dyes [J].

Liu, Sen ;

Tian, Jingqi ;

Wang, Lei ;

Luo, Yonglan ;

Sun, Xuping .

CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (02) :339-344

[10] Solvent Free Selective Oxidation of Styrene and Benzyl Alcohol to Benzaldehyde over an Eco-Friendly and Reusable Catalyst, Undecamolybdophosphate Supported onto Neutral Alumina [J].

Patel, Anjali ;

Pathan, Soyeb .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (02) :732-740

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