Sonogashira cross-coupling reactions with heteroaryl halides in the presence of a tetraphosphine-palladium catalyst

被引：49

作者：

Feuerstein, M

Doucet, H

Santelli, M

机构：

[1] CNRS, Organ Synth Lab, UMR 6180, F-13397 Marseille 20, France

[2] Univ Aix Marseille 3, F-13397 Marseille 20, France

[3] Fac Sci & Tech St Jerome, F-13397 Marseille 20, France

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 10期

关键词：

palladium; catalysis; heteroaryl halide; alkyne; Sonogashira reaction; tetraphosphine;

D O I：

10.1016/j.tetlet.2005.01.044

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heteroaryl halides undergoes cross-couplings with alkynes in good yields in the presence of [PdCl(C3H5)](2)/cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane as catalyst. A variety of heteroaryl halides such as pyridines, quinolines, a pyrimidine, an indole, a thiophene, or a thiazole have been used successfully. The reaction also tolerates several alkynes such as phenylacetylene and a range of alk-l-ynols. Furthermore, this catalyst can be used at low loading with some substrates. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1717 / 1720

页数：4

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