Microwave assisted hydrothermal synthesis of a novel CuI-sulfate-pyrazine MOF

被引：87

作者：

Amo-Ochoa, Pilar

Givaja, Gonzalo

Miguel, Pablo J. Sanz

Castillo, Oscar

Zamora, Felix ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Inorgan, E-28049 Madrid, Spain

[2] Univ Alfonso X El Sabio, Dept Technol Ind, Madrid 28691, Spain

[3] Univ Basque Country, Fac Ciencias & Tecnol, Dept Quim Inorgan, E-48080 Bilbao, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 08期

关键词：

coordination polymer; interpenetrating networks; microwave synthesis; hydrothermal synthesis; MOF;

D O I：

10.1016/j.inoche.2007.04.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D coordination copper polymer has been synthesised under microwave heating hydrothermal conditions. Microwave irradiation reduces the time of reaction considerably, suggesting the effectiveness of this methodology in the synthesis of metal-organic frameworks. It is noteworthy that microwave assisted synthesis produces monocrystals suitable for X-ray diffraction studies, reducing reaction time and with higher yield than the classical hydrothermal procedures. The compound presented here, [CU2(pyz)(2)(SO4)(H2O)(2)](n) (pyz = pyrazine), has been crystallographically characterised to be a threefold interpenetrated three-dimensional coordination (10,3)-b network. (c) 2007 Elsevier B. V. All rights reserved.

引用

页码：921 / 924

页数：4

共 27 条

[1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].