Self-supported formatnion of needlelike Co3O4 nanotubes and their application as lithium-ion battery electrodes

被引:951
作者
Lou, Xiong Wen [1 ]
Deng, Da [2 ]
Lee, Jim Yang [2 ]
Feng, Ji [3 ]
Archer, Lynden A. [1 ]
机构
[1] Cornell Univ, Sch Chem & Biomol Engn, Ithaca, NY 14853 USA
[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore
[3] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
关键词
D O I
10.1002/adma.200702412
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A one-step, self-supported topotactic transformation approach for synthesizing electrochemically active Co3O4 needlelike nanotubes is reported. Used as the active material in the negative electrode of a rechargeable lithium ion battery, the Co3O4 nanotubes manifest ultrahigh Li storage capacity with improved cycle life and rate capability. These features are discussed in terms of the unique structure of the materials.
引用
收藏
页码:258 / +
页数:6
相关论文
共 39 条
  • [1] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377
  • [2] Synthesis, characterization, and li-electrochemical performance of highly porous Co3O4 powders
    Binotto, G.
    Larcher, D.
    Prakash, A. S.
    Urbina, R. Herrera
    Hegde, M. S.
    Tarascon, J-M.
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (12) : 3032 - 3040
  • [3] Supportless Pt and PtPd nanotubes as electrocatalysts for oxygen-reduction reactions
    Chen, Zhongwei
    Waje, Mahesh
    Li, Wenzhen
    Yan, Yushan
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (22) : 4060 - 4063
  • [4] Monocrystalline spinel nanotube fabrication based on the Kirkendall effect
    Fan, Hong Jin
    Knez, Mato
    Scholz, Roland
    Nielsch, Kornelius
    Pippel, Eckhard
    Hesse, Dietrich
    Zacharias, Margit
    Goesele, Ulrich
    [J]. NATURE MATERIALS, 2006, 5 (08) : 627 - 631
  • [5] Size-controlled growth of Co3O4 nanocubes
    Feng, J
    Zeng, HC
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (14) : 2829 - 2835
  • [6] Single-crystal gallium nitride nanotubes
    Goldberger, J
    He, RR
    Zhang, YF
    Lee, SW
    Yan, HQ
    Choi, HJ
    Yang, PD
    [J]. NATURE, 2003, 422 (6932) : 599 - 602
  • [7] High-rate, long-life Ni-Sn nanostructured electrodes for lithium-ion batteries
    Hassoun, Jusef
    Panero, Stefania
    Simon, Patrice
    Taberna, Pierre Louis
    Scrosati, Bruno
    [J]. ADVANCED MATERIALS, 2007, 19 (12) : 1632 - +
  • [8] Co3O4 nanoboxes:: Surfactant-templated fabrication and microstructure characterization
    He, T
    Chen, DR
    Jiao, XL
    Wang, YL
    [J]. ADVANCED MATERIALS, 2006, 18 (08) : 1078 - +
  • [9] High-yield preparation of uniform cobalt hydroxide and oxide nanoplatelets and their characterization
    Hou, YL
    Kondoh, H
    Shimojo, M
    Kogure, T
    Ohta, T
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (41) : 19094 - 19098
  • [10] Synthesis of crystalline silicon tubular nanostructures with ZnS nanowires as removable templates
    Hu, JQ
    Bando, Y
    Liu, ZW
    Zhan, JH
    Golberg, D
    Sekiguchi, T
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (01) : 63 - 66