Self-supported formatnion of needlelike Co3O4 nanotubes and their application as lithium-ion battery electrodes

被引:953
作者
Lou, Xiong Wen [1 ]
Deng, Da [2 ]
Lee, Jim Yang [2 ]
Feng, Ji [3 ]
Archer, Lynden A. [1 ]
机构
[1] Cornell Univ, Sch Chem & Biomol Engn, Ithaca, NY 14853 USA
[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore
[3] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
关键词
D O I
10.1002/adma.200702412
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A one-step, self-supported topotactic transformation approach for synthesizing electrochemically active Co3O4 needlelike nanotubes is reported. Used as the active material in the negative electrode of a rechargeable lithium ion battery, the Co3O4 nanotubes manifest ultrahigh Li storage capacity with improved cycle life and rate capability. These features are discussed in terms of the unique structure of the materials.
引用
收藏
页码:258 / +
页数:6
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