The influence of the temperature on the liquid-liquid equilibrium of the ternary system 1-butanol-1-propanol-water

被引:19
作者
Gomis-Yagues, V [1 ]
Ruiz-Bevia, F [1 ]
Ramos-Nofuentes, M [1 ]
Fernandez-Torres, MJ [1 ]
机构
[1] Univ Alicante, Dept Ingn Quim, E-03080 Alicante, Spain
关键词
data; liquid-liquid equilibria; temperature; UNIQUAC; correlation;
D O I
10.1016/S0378-3812(98)00315-X
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid equilibrium data for the ternary system l-butanol-l-propanol-water have been determined experimentally at 25, 50, 85 and 95 degrees C. The results obtained have been correlated simultaneously by the UNIQUAC method obtaining two sets of interaction parameters: one of them independent of the temperature and the other with a linear dependence. Both sets of parameters fit the experimental results well which is an improvement on using parameters depending of the temperature of 15%. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:139 / 145
页数:7
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