Synthesis, characterization and thermal behaviour of guanidinium-5-aminotetrazolate (GA) -: A new nitrogen-rich compound

被引:77
作者
Neutz, J [1 ]
Grosshardt, O [1 ]
Schäufele, S [1 ]
Schuppler, H [1 ]
Schweikert, W [1 ]
机构
[1] Fraunhofer Inst Chem Technol, D-76327 Pfinztal, Germany
关键词
guanidinium-5-aminotetrazolate (GA); synthesis; thermoanalysis; decomposition;
D O I
10.1002/prep.200300003
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This work describes the synthesis and the thermoanalytical characterization of guanidinium-5-aminotetrazolate (GA). GA is a new nitrogen-rich energetic material. It is not mentioned in the chemical literature so far. The molecular structure of the compound has been determined by IR, H-1-, C-13- and N-15-NMR spectroscopy. The thermal properties, the decomposition pathways and its volatile products were investigated by thermal analysis and are discussed.
引用
收藏
页码:181 / 188
页数:8
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