Conical intersections as forking points in an ultrafast photoinduced chemical reaction

被引：0

作者：

Hofmann, A ^{[1
]}

De Vivie-Riedle, R ^{[1
]}

机构：

[1] Max Planck Inst Quantum Opt, D-85748 Garching, Germany

来源：

JOURNAL OF INFORMATION RECORDING | 2000年 / 25卷 / 3-4期

关键词：

conical intersections; ultrafast quantum dynamics; bifurcation;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The photoinduced ringopening of cyclohexadiene to hexatriene occurs on a femtosecond time scale. The observed fast non-radiative transition from the excited state Si to the ground state S-0 is only possible when the molecular system leaves the Woddward-Hoffmann defined reactionpath. To gain physical insight of this process on a microscopic scale we investigate the molecular motion on the excited S-1 state by means of wavepacket propagations.

引用

页码：397 / 403

页数：7

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