A NdIIICuII molecular material with a honeycomb-like structure

被引：50
作者：
Daiguebonne, C
Guillou, O [1 ]
Kahn, ML
Kahn, O
Oushoorn, RL
Boubekeur, K
机构：
[1] Inst Natl Sci Appl, Grp Rech Chim & Met, F-35043 Rennes, France
[2] Inst Chim Mat Condensee, UPR CNRS 9048, Lab Sci Mol, F-63608 Pessac, France
[3] Inst Mat Jean Rouxel, FRE 2068 CNRS, F-44322 Nantes 3, France
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 01期
关键词：
D O I：
10.1021/ic000375l
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first two-dimensional molecular material Nd(III)-Cu(II) has been synthesized by reaction in DMF of [Cu(opba)](2-) and Nd3+. The compound {Nd-2[Cu(opba)(0.5)(ox)](3). 9DMF}.4.5DMF has been structurally characterized. Its crystalline structure can be described as the superposition of honeycomb-like molecular motifs. This material exhibits a quasi nonmagnetic ground state at low temperature.
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页码：176 / +
页数：4
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