A NdIIICuII molecular material with a honeycomb-like structure

被引：50

作者：

Daiguebonne, C

Guillou, O ^{[1
]}

Kahn, ML

Kahn, O

Oushoorn, RL

Boubekeur, K

机构：

[1] Inst Natl Sci Appl, Grp Rech Chim & Met, F-35043 Rennes, France

[2] Inst Chim Mat Condensee, UPR CNRS 9048, Lab Sci Mol, F-63608 Pessac, France

[3] Inst Mat Jean Rouxel, FRE 2068 CNRS, F-44322 Nantes 3, France

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 01期

关键词：

D O I：

10.1021/ic000375l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first two-dimensional molecular material Nd(III)-Cu(II) has been synthesized by reaction in DMF of [Cu(opba)](2-) and Nd3+. The compound {Nd-2[Cu(opba)(0.5)(ox)](3). 9DMF}.4.5DMF has been structurally characterized. Its crystalline structure can be described as the superposition of honeycomb-like molecular motifs. This material exhibits a quasi nonmagnetic ground state at low temperature.

引用

页码：176 / +

页数：4

共 23 条

[1] Dc and ac magnetic properties of the two-dimensional molecular-based ferrimagnetic materials A(2)M(2)[Cu(opba)](3)center dot nsolv [A(+)=cation, M-II=Mn-II or Co-II, opba equals ortho-phenylenebis(oxamato) and solv equals solvent molecule] [J].