Geochronology and geochemistry of multiple generations of monazite from the Wepawaug Schist, Connecticut, USA: Implications for monazite stability in metamorphic rocks

被引:95
作者
Lanzirotti, A
Hanson, GN
机构
[1] Department of Earth Sciences, State Univ. New York at Stony Brook, Stony Brook
关键词
D O I
10.1007/s004100050226
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
U-Pb isotope analyses, rare earth and trace element analyses, and petrographic observations are presented for monazites from the Wepawaug Schist in southern Connecticut, USA. Two samples of kyanite zone schist were collected less than a meter apart. Each sample contains a different variety of monazite with distinct morphology, chemistry, and Pb isotopic composition. One sample preserves a largely amphibolite facies mineralogy, including kyanite, staurolite, garnet, biotite, and chlorite, with little textural evidence of later shearing. Monazites from this sample are xenoblastic with about 1 wt% ThO2, 0.3 wt% CaO, and a more LREE enriched pattern than monazites from the second sample. These xenoblastic monazites preserve textural evidence of a retrograde reaction to apatite which involves chlorite, indicating that these monazites became unstable during retrograde chloritization of biotite. These monazites give strongly discordant U-Pb ages which fit a chord with an upper intercept age of 411 +/- 18 Ma, interpreted as the minimum growth age of these xenoblastic monazites, perhaps during amphibolite facies metamorphism. The second sample contains S-C banding, evidence of dynamic recrystallization, and abundant retrograde chlorite. This sample contains idioblastic monazites with about 3 wt% ThO2, 0.8 wt% CaO, and with less fractionated REE patterns. These monazites give close to concordant U-Pb ages with a mean Pb-207*/Pb-206* age of 388 +/- 2 Ma. This age is interpreted as probably representing the time of retrogression of the sample from an amphibolite to greenschist facies mineralogy.
引用
收藏
页码:332 / 340
页数:9
相关论文
共 28 条
[2]   THE INSTABILITY OF RHABDOPHANE AND ITS UNIMPORTANCE IN MONAZITE PARAGENESIS [J].
AKERS, WT ;
GROVE, M ;
HARRISON, TM ;
RYERSON, FJ .
CHEMICAL GEOLOGY, 1993, 110 (1-3) :169-176
[3]  
BONS AJ, 1988, THESIS RIJKUNIVERSIT
[4]   MASS SPECTROMETRY OF NANOGRAM-SIZE SAMPLES OF LEAD [J].
CAMERON, AE ;
SMITH, DH ;
WALKER, RL .
ANALYTICAL CHEMISTRY, 1969, 41 (03) :525-&
[5]   NEW RARE-EARTH ELEMENT STANDARDS FOR ELECTRON-MICROPROBE ANALYSIS [J].
DRAKE, MJ ;
WEILL, DF .
CHEMICAL GEOLOGY, 1972, 10 (02) :179-&
[6]  
EGGLETON RA, 1985, AM MINERAL, V70, P902
[7]  
FRITTS CE, 1962, THESIS U MICHIGAN
[8]   MONAZITE PARAGENESIS AND U-PB SYSTEMATICS IN ROCKS OF THE EASTERN MOJAVE DESERT, CALIFORNIA, USA - IMPLICATIONS FOR THERMOCHRONOMETRY [J].
KINGSBURY, JA ;
MILLER, CF ;
WOODEN, JL ;
HARRISON, TM .
CHEMICAL GEOLOGY, 1993, 110 (1-3) :147-167
[9]   LOW-CONTAMINATION METHOD FOR HYDROTHERMAL DECOMPOSITION OF ZIRCON AND EXTRACTION OF U AND PB FOR ISOTOPIC AGE DETERMINATIONS [J].
KROGH, TE .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1973, 37 (03) :485-494
[10]   U-PB DATING OF MAJOR AND ACCESSORY MINERALS FORMED DURING METAMORPHISM AND DEFORMATION OF METAPELITES [J].
LANZIROTTI, A ;
HANSON, GN .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1995, 59 (12) :2513-2526