Synthesis and Crystal Structures of t-Butyl-Pyridine Adducts of ZnR2 (R = Me, i-Pr, t-Bu, Cp*)

被引：2

作者：

Schulz, Stephan ^{[1
]}

Schaeper, Raphaela ^{[1
]}

Krech, Daniel ^{[1
]}

Schuchmann, Daniella ^{[1
]}

Blaeser, Dieter ^{[1
]}

Boese, Roland ^{[1
]}

机构：

[1] Univ Duisburg Essen, Inst Inorgan Chem, D-45117 Essen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 01期

关键词：

Zinc; Lewis acids; Lewis bases; X-ray Structures; Pyridine; METAL-MEDIATED ZINCATION; KOORDINATIONSCHEMISCHE UNTERSUCHUNGEN; ORGANOMETALLIC COMPOUNDS; ELECTRON-DIFFRACTION; MOLECULAR-STRUCTURES; TMP-ZINCATE; DIMETHYLZINC; COMPLEXES; AMIDO; ALKYL;

D O I：

10.1002/zaac.201000264

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lewis acid-base adducts of the general type R2Zn(4-tBuPy)(x) (R = Me 1, iPr 2, tBu 3, Cp* 4; x = 1, 2) were obtained in high yields from reactions of ZnR2 with the Lewis base 4-tBu-Pyridine. Compounds 1-4 were characterized by multinuclear NMR (H-1, C-13) and IR spectroscopy and elemental analyses, 1 and 4 also by X-ray diffraction at single crystals.

引用

页码：83 / 86

页数：4

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