[CoCl(TPPyP)], a novel bifunctional catalyst for the coupling reaction of carbon dioxide and propylene oxide

被引：0

作者：

Ren, Tiegang ^{[1
]}

Li, Weijie ^{[1
]}

Bu, Zhanwei ^{[1
,2
]}

Yang, Lirong ^{[1
]}

Wang, Zhiqiang ^{[1
]}

机构：

[1] Henan Univ, Fine Chem & Engn Res Inst, Kaifeng 475004, Henan, Peoples R China

[2] Henan Tianguan Enterprise Grp Co Ltd, Nanyang 473000, Henan, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2010年 / 07期

关键词：

chloro[meso-tetrakis(1-phenylpyrazol-4-yl)porphyrin]cobalt(III); carbon dioxide; propylene oxide; propylene carbonate; bifunctional catalyst; CYCLIC CARBONATE; ALTERNATING COPOLYMERIZATION; ALUMINUM PORPHYRIN; CHEMICAL FIXATION; COBALT PORPHYRIN; MOLECULAR-WEIGHT; BASE CATALYSTS; EPOXIDES; CO2; SYSTEM;

D O I：

10.3184/030823410X12762744367622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel bifunctional catalyst chloro[meso-tetrakis(1-phenylpyrazol-4-yl)porphyrin] cobalt (III), [CoCl(TPPyP)], has been prepared and used to catalyse the synthesis of propylene carbonate from carbon dioxide and propylene oxide under mild conditions. Propylene carbonate was obtained with a yield of 25.2% at 100 degrees C in the absence of co-catalyst. A reaction mechanism is proposed.

引用

页码：361 / 364

页数：4

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