Triphenylamine-based organic small-molecule interlayer materials for inverted perovskite solar cells

被引：8
作者：
Doyranli, Ceylan [1 ]
Choi, Fatma Pinar Gokdemir [2 ]
Alishah, Hamed Moeini [2 ]
Koyuncu, Sermet [3 ,4 ]
Gunes, Serap [2 ]
San, Nevim [1 ]
机构：
[1] Yildiz Tech Univ, Fac Arts & Sci, Dept Chem, Davutpasa Campus, TR-34210 Istanbul, Turkey
[2] Yildiz Tech Univ, Fac Arts & Sci, Dept Phys, Davutpasa Campus, TR-34210 Istanbul, Turkey
[3] Canakkale Onsekiz Mart Univ, Fac Engn, Dept Chem Engn, TR-17100 Canakkale, Turkey
[4] Canakkale Onsekiz Mart Univ, Dept Energy Resources & Management, TR-17020 Canakkale, Turkey
来源：
ORGANIC ELECTRONICS | 2022年 / 108卷
关键词：
Hole transport layer; Inverted perovskite solar cells; Interlayer materials; Donor-acceptor-donor type organic small; molecules; HOLE-TRANSPORTING MATERIALS; SURFACE MODIFICATION; INTERFACIAL LAYER; LOW-COST; OXIDE; PERFORMANCE; EFFICIENT; DEFECT; AIR;
D O I：
10.1016/j.orgel.2022.106595
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this report, two novel donor-acceptor-donor type triphenylamine-quinoxaline-based (QC-TPA and QC-TPAOMe) small organic molecules have been synthesized by the Suzuki coupling reaction as hole transport materials (HTMs) and successfully utilized in the NiOx/perovskite interface. All device fabrication steps with ITO/NiOx/QC-TPA or QC-TPAOMe/CH3NH3PbI3/PCBM/BCP/Ag configurations were performed in ambient air over 55% relative humidity, except for thermal evaporation of metal contacts. Modifications of the NiOx/ perovskite interface with QC-TPA and QC-TPAOMe molecules can improve FF and JSC by enhancing hole extraction and reducing energy losses. Consequently, the power conversion efficiency (PCE) boosted from 10.03% to 14.46% and 13.21% with surface modifications of NiOx with QC-TPA and QC-TPAOMe, respectively.
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页数：10
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