Self-Assembled Capsules of Unprecedented Shapes

被引:27
|
作者
Tiefenbacher, Konrad [1 ,2 ]
Ajami, Dariush [1 ,2 ]
Rebek, Julius, Jr. [1 ,2 ]
机构
[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
基金
奥地利科学基金会;
关键词
host-guest systems; molecular capsules; molecular recognition; reversible encapsulation; self-assembly; DIELS-ALDER; MOLECULAR RECOGNITION; REVERSIBLE ENCAPSULATION; GUESTS; STABILIZATION; CATALYSIS;
D O I
10.1002/anie.201102548
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Curved hosts: The first examples of bent molecular capsules are described: They feature banana or S shapes (see picture) and are capable of selectively binding complementary shaped guests. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:12003 / 12007
页数:5
相关论文
共 50 条
  • [41] Supramolecular Catalysis with Self-Assembled Capsules and Cages: What Happens in Confined Spaces
    Gaeta, Carmine
    La Manna, Pellegrino
    De Rosa, Margherita
    Soriente, Annunziata
    Talotta, Carmen
    Neri, Placido
    CHEMCATCHEM, 2021, 13 (07) : 1638 - 1658
  • [42] Bioencapsulation of probiotics with self-assembled DNA capsules for the treatment of inflammatory bowel diseases
    Chang, Yongliang
    Wang, Kairuo
    Zhou, Mengting
    Miao, Yunqiu
    Wu, Xiawei
    Chen, Qian
    Zhang, Yuanyuan
    Zhu, Xiaoli
    Mao, Dongsheng
    Zhang, Yang
    Qin, Huanlong
    CHEMICAL ENGINEERING JOURNAL, 2024, 499
  • [43] Self-assembled hydrogen-bonded dimeric capsules with high kinetic stability
    Vysotsky, MO
    Thondorf, I
    Böhmer, V
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (07) : 1264 - +
  • [44] Self-assembled nanostructure of Au nanoparticles on a self-assembled monolayer
    Wakamatsu, S
    Nakada, J
    Fujii, S
    Akiba, U
    Fujihira, M
    ULTRAMICROSCOPY, 2005, 105 (1-4) : 26 - 31
  • [45] Unprecedented self-assembled architectures of surface-active ionic liquids in aqueous medium
    Singh, Gurbir
    Kaur, Manvir
    Drechsler, Markus
    Kang, Tejwant Singh
    CHEMICAL COMMUNICATIONS, 2018, 54 (19) : 2432 - 2435
  • [46] An Unprecedented Self-Assembled Porous Framework Constructed by Intermolecular S...S Contacts
    Son, Kyung-In
    Lee, Ha-Jin
    Kim, Jaheon
    Noh, Dong-Youn
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (08) : 2773 - 2776
  • [47] Two unprecedented aromatic guanidines supramolecular chains self-assembled by hydrogen bonding interaction
    Zhang, Yunshen
    Huang, Yichao
    Zhang, Jiangwei
    Zhu, Li
    Chen, Kun
    Hao, Jian
    JOURNAL OF MOLECULAR STRUCTURE, 2015, 1097 : 145 - 150
  • [48] Electronic structure of Ge/Si self-assembled quantum dots with different shapes
    Kim, JY
    Seok, JH
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2002, 89 (1-3): : 176 - 179
  • [49] Complex shapes self-assembled from single-stranded DNA tiles
    Wei, Bryan
    Dai, Mingjie
    Yin, Peng
    NATURE, 2012, 485 (7400) : 623 - +
  • [50] Are they truly capsules? Computed structures of self-assembled molecular complexes in polar solvents.
    Mardis, KL
    Hoge, EM
    Larson, KC
    Nguyen, LPT
    Smith, JM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U221 - U221