Emerging unconventional organic solvents for C-H bond and related functionalization reactions

被引：95

作者：

Yu, Congjun ^{[1
]}

Sanjose-Orduna, Jesus ^{[2
]}

Patureau, Frederic W. W. ^{[1
]}

Perez-Temprano, Monica H. ^{[2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany

[2] Inst Chem Res Catalonia ICIQ, Avinguda Dels Paisos Catalans 16, Tarragona 43007, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2020年 / 49卷 / 06期

关键词：

ALKENYLATION; ACCESS; HEXAFLUOROISOPROPANOL; ALKYLATION; CONVERSION; AMINATION; OXIDATION; ALCOHOLS; CATALYST; ARENES;

D O I：

10.1039/c8cs00883c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvent engineering is an increasingly essential topic in the chemical sciences. In this context, some recently appeared unconventional solvents have shown their large potential in the field of C-H bond functionalization reactions. This review aims not only at recognizing and classifying a short selection of these emerging solvents, in particular halogenated ones, but also at providing a medium term perspective of the possibilities they will offer for synthetic method development.

引用

页码：1643 / 1652

页数：10

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