Effect of Aging on Surface Chemistry of Rice Husk-Derived Biochar

被引：35
作者：
Huang, Zhaoqin [1 ,2 ]
Hu, LinChao [3 ,4 ]
Zhou, Qiang [1 ]
Guo, Yue [1 ]
Tang, Wei [1 ]
Dai, Jingyu [1 ]
机构：
[1] Nanjing Agr Univ, Coll Resources & Environm Sci, Nanjing 210095, Jiangsu, Peoples R China
[2] JiangSu Open Univ, Coll Environm & Ecol, Nanjing 210036, Jiangsu, Peoples R China
[3] Changzhou Acad Environm Sci, Dept Engn, Changzhou 213022, Peoples R China
[4] Changzhou Univ, Sch Environm & Safety Engn, Changzhou 213164, Peoples R China
来源：
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY | 2018年 / 37卷 / 01期
基金：
中国国家自然科学基金;
关键词：
biochar; aging; surface property; rice husk; DIFFERENT PYROLYTIC TEMPERATURES; BLACK CARBON; EXCHANGE CAPACITY; ORGANIC-CARBON; SOIL AMENDMENT; XPS ANALYSIS; ADSORPTION; OXIDATION; SPECTROSCOPY; CHARCOALS;
D O I：
10.1002/ep.12694
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Herein, we aimed to determine the physicochemical properties of biochar produced from rice husk at 350 and 550 degrees C, to characterize changes in the biochar properties during aging and to identify the effect of aging time on these changes. To simulate different stages in the aging process, samples were incubated at a constant temperature in the dark and maintained at 60% water holding capacity for 100-300 d. The transformation and morphology of the biochar particles were monitored by diffuse-reflectance Fourier transform infrared spectroscopy (DRIFTS), scanning electron microscopy (SEM) coupled with energy X-ray dispersive spectroscopy, and X-ray photoelectron spectroscopy (XPS). During aging, a layer formed on the surface and the content of easily oxidized substances increased with increased aging time. In addition, SEM indicated that oxidation occurred close to the biochar surface rather than in the biochar particle interior. Furthermore, the DRIFTS and XPS results indicated that the biochar surface produced at 550 degrees C underwent decarboxylation and hydroxylation, while for the 350 degrees C biochar, the increase in surface oxygen content was associated with the presence of hydroxyl moieties. (c) 2017 American Institute of Chemical Engineers
引用
收藏
页码：410 / 417
页数：8
相关论文
共 35 条
[1]   XPS analysis of chemical functions at the surface of Bacillus subtilis [J].
Ahimou, Francois ;
Boonaert, Christophe J. P. ;
Adriaensen, Yasmine ;
Jacques, Philippe ;
Thonart, Philippe ;
Paquot, Michel ;
Rouxhet, Paul G. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 309 (01) :49-55
[2]  
[Anonymous], THESIS
[3]   Variability in oxidative degradation of charcoal: Influence of production conditions and environmental exposure [J].
Ascough, P. L. ;
Bird, M. I. ;
Francis, S. M. ;
Thornton, B. ;
Midwood, A. J. ;
Scott, A. C. ;
Apperley, D. .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2011, 75 (09) :2361-2378
[4]   The characterization of activated carbons with oxygen and nitrogen surface groups [J].
Biniak, S ;
Szymanski, G ;
Siedlewski, J ;
Swiatkowski, A .
CARBON, 1997, 35 (12) :1799-1810
[5]   Morphological and chemical properties of black carbon in physical soil fractions as revealed by scanning electron microscopy and energy-dispersive X-ray spectroscopy [J].
Brodowski, S ;
Amelung, W ;
Haumaier, L ;
Abetz, C ;
Zech, W .
GEODERMA, 2005, 128 (1-2) :116-129
[6]   Dairy-Manure Derived Biochar Effectively Sorbs Lead and Atrazine [J].
Cao, Xinde ;
Ma, Lena ;
Gao, Bin ;
Harris, Willie .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (09) :3285-3291
[7]   Agronomic values of greenwaste biochar as a soil amendment [J].
Chan, K. Y. ;
Van Zwieten, L. ;
Meszaros, I. ;
Downie, A. ;
Joseph, S. .
AUSTRALIAN JOURNAL OF SOIL RESEARCH, 2007, 45 (08) :629-634
[8]   Sorption of naphthalene and 1-naphthol by biochars of orange peels with different pyrolytic temperatures [J].
Chen, Baoliang ;
Chen, Zaiming .
CHEMOSPHERE, 2009, 76 (01) :127-133
[9]   Natural oxidation of black carbon in soils: Changes in molecular form and surface charge along a climosequence [J].
Cheng, Chih-Hsin ;
Lehmann, Johannes ;
Engelhard, Mark H. .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2008, 72 (06) :1598-1610
[10]   Oxidation of black carbon by biotic and abiotic processes [J].
Cheng, Chih-Hsin ;
Lehmann, Johannes ;
Thies, Janice E. ;
Burton, Sarah D. ;
Engelhard, Mark H. .
ORGANIC GEOCHEMISTRY, 2006, 37 (11) :1477-1488
1234