[Fe(SCN)2(bipy)2]•2(S8): A two-dimensional coordination polymer intercalating the S8 molecules

被引：3
|
作者：
Hao, Min-Ting [1 ,2 ]
Du, Cheng-Feng [2 ]
Tian, Chong-Bin [2 ]
Li, Jian-Rong [2 ]
Huang, Xiao-Ying [2 ]
机构：
[1] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 72卷
关键词：
Coordination polymer; S-8; molecules; Iron(II); Layered structure; Magnetic properties; LI-S BATTERIES; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; ELEMENTAL SULFUR; ADDITION COMPLEX; CYCLO-OCTASULFUR; RAMAN-SPECTRA; C-60-CENTER-DOT-2S(8); COMPOUND;
D O I：
10.1016/j.inoche.2016.08.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer compound [Fe(SCN)(2)(bipy)(2)]center dot 2(S-8) (1) (bipy = 4,4'-bipyridine) has been synthesized by the reaction of the bifunctional ligand bipy, Fe(SCN)2 and sulfur powder under hydrothermal conditions. The compound has been characterized by single and powder X-ray diffraction analysis, infrared spectroscopy and elemental analysis. Compound 1 features a two-dimensional layered structure with neutral S-8 molecules confined in between layers. The magnetic property studies of 1 indicated antiferromagnetic interactions. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：128 / 131
页数：4
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