Studies towards the total synthesis of (-)-callystatin A

被引：10
|
作者：
Yadav, J. S. [1 ]
Yadagiri, K. [1 ]
Madhuri, Ch. [1 ]
Sabitha, G. [1 ]
机构：
[1] Indian Inst Chem Technol, CSIR, Div Organ Chem, Hyderabad 500607, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 33期
关键词：
(-)-Callystatin A; Desymmetrization; Wadsworth-Emmons reaction; Cross-metathesis; POTENT CYTOTOXIC POLYKETIDE; ASYMMETRIC TOTAL-SYNTHESIS; MARINE SPONGE; CALLYSTATIN-A; PARTICIPATION; PART;
D O I：
10.1016/j.tetlet.2011.05.151
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of C-1-C-12 and C-13-C-22 fragments of (-)-callystatin A is accomplished employing desymmetrization strategy for the creation of five chiral centers of the polypropionate fragment and application of cross-metathesis (CM) reaction for the first time for this molecule. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4269 / 4272
页数：4
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