Enhanced electron transfer and ion storage in phosphorus/nitrogen co-doped 3D interconnected carbon nanocage toward potassium-ion battery

Heteroatoms doping strategies are often considered to be an effective approach to provide rich active sites for capacitive-controlled potassium storage, and enlarged interspacing for intercalation process. However, the excess doping level will form a large number of sp(3) defects and thus severely damage pi-conjugated system, which is unfavorable for electron transfer. Herein, a P/N co-doped three-dimensional (3D) interconnected carbon nanocage (denoted as PN-CNC) is prepared with the help of a template-assisted method. The use of template and P heteroatom can contribute to forming a 3D interconnected carbon nanocage to prevent conductive carbon matrix from being excessively damaged, favoring a high electronic conductivity. The co-existence of P/N doping configurations with suitable content not only generate abundant defects, edge-voids, and micropores for significant capacitive behaviors, but also supply adequate interlayer space for intercalation process, and all these together ensure enhanced ion storage. As a result, the optimized PN-CNC electrode exhibits an exceptional reversible capacity (262 mAh g(-1)) and a superior rate capability (214.2 mAh g(-1)). Besides, long-term cycling stability is easily fulfilled by delivering a high capacity of 188.7 mAh g(-1) at 2 A g(-1) after 3000 cycles. (C) 2021 Elsevier Inc. All rights reserved.