Synthesis of nitrogen and sulfur co-doped hierarchical porous carbons and metal-free oxidative coupling of silanes with alcohols

被引:10
作者
Chen, Bingfeng [1 ]
Li, Fengbo [2 ]
Mei, Qingqing [1 ]
Yang, Youdi [1 ,3 ]
Liu, Huizhen [1 ,3 ]
Yuan, Guoqing [2 ]
Han, Buxing [1 ,3 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Chem, CAS Key Lab Green Printing, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
OXYGEN REDUCTION REACTION; SELECTIVE OXIDATION; GOLD NANOPARTICLES; CATALYTIC-ACTIVITY; AEROBIC OXIDATION; BOND ACTIVATION; GRAPHENE; SILYLATION; BATTERIES; PHENOLS;
D O I
10.1039/c7cc07931a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hierarchically porous N and S co-doped carbon was prepared by using 2,5-dihydroxy-1,4-benzoquinone as the carbon source, thiourea as the N and S source, and SiO2 particles as the template. Using the material as the catalyst, oxidative coupling of silanes with alcohols was conducted for the first time under metal-free conditions.
引用
收藏
页码:13019 / 13022
页数:4
相关论文
共 41 条
[1]   Copper Nanoparticles Supported on Doped Graphenes as Catalyst for the Dehydrogenative Coupling of Silanes and Alcohols [J].
Blandez, Juan F. ;
Primo, Ana ;
Asiri, Abdullah M. ;
Alvaro, Mercedes ;
Garcia, Hermenegildo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (46) :12581-12586
[2]   Intrinsic Relationship between Enhanced Oxygen Reduction Reaction Activity and Nanoscale Work Function of Doped Carbons [J].
Cheon, Jae Yeong ;
Kim, Jong Hun ;
Kim, Jae Hyung ;
Goddeti, Kalyan C. ;
Park, Jeong Young ;
Joo, Sang Hoon .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (25) :8875-8878
[3]   Dehydrogenative coupling of silanes with alcohols catalyzed by Cu3(BTC)2 [J].
Dhakshinamoorthy, Amarajothi ;
Concepcion, Patricia ;
Garcia, Hermenegildo .
CHEMICAL COMMUNICATIONS, 2016, 52 (13) :2725-2728
[4]   Sulphur-doped graphene as metal-free carbocatalysts for the solventless aerobic oxidation of styrenes [J].
Dhakshinamoorthy, Amarajothi ;
Latorre-Sanchez, Marcos ;
Asiri, Abdullah M. ;
Primo, Ana ;
Garcia, Hermenegildo .
CATALYSIS COMMUNICATIONS, 2015, 65 :10-13
[5]   Multiple roles of graphene in heterogeneous catalysis [J].
Fan, Xiaobin ;
Zhang, Guoliang ;
Zhang, Fengbao .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (10) :3023-3035
[6]   Hierarchical Nanostructured Carbons with Meso-Macroporosity: Design, Characterization, and Applications [J].
Fang, Baizeng ;
Kim, Jung Ho ;
Kim, Min-Sik ;
Yu, Jong-Sung .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (07) :1397-1406
[7]   Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content [J].
Fechler, Nina ;
Zussblatt, Niels P. ;
Rothe, Regina ;
Schloegl, Robert ;
Willinger, Marc-Georg ;
Chmelka, Bradley F. ;
Antonietti, Markus .
ADVANCED MATERIALS, 2016, 28 (06) :1287-1294
[8]   Nitrogen-Doped sp2-Hybridized Carbon as a Superior Catalyst for Selective Oxidation [J].
Gao, Yongjun ;
Hu, Gang ;
Zhong, Jun ;
Shi, Zujin ;
Zhu, Yuanshuai ;
Su, Dang Sheng ;
Wang, Jianguo ;
Bao, Xinhe ;
Ma, Ding .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (07) :2109-2113
[9]   Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts [J].
Guo, Donghui ;
Shibuya, Riku ;
Akiba, Chisato ;
Saji, Shunsuke ;
Kondo, Takahiro ;
Nakamura, Junji .
SCIENCE, 2016, 351 (6271) :361-365
[10]   Structure and electrical conductivity of nitrogen-doped carbon nanofibers [J].
Ismagilov, Zinfer R. ;
Shalagina, Anastasia E. ;
Podyacheva, Olga Yu. ;
Ischenko, Arkady V. ;
Kibis, Lidiya S. ;
Boronin, Andrey I. ;
Chesalov, Yury A. ;
Kochubey, Dmitry I. ;
Romanenko, Anatoly I. ;
Anikeeva, Olga B. ;
Buryakov, Timofey I. ;
Tkachev, Evgeniy N. .
CARBON, 2009, 47 (08) :1922-1929