Formation of Refractory Carbide and Nitride Nanofibers by Thermal Decomposition of Poly(vinyl alcohol)-Titanium Lactate Hybrid Nanofibers

被引：4
作者：
Nakane, Koji [1 ]
Nakanishi, Keisuke [1 ]
Kim, Jae-Ho [1 ]
Yonezawa, Susumu [1 ]
Ogihara, Takashi [1 ]
Ogata, Nobuo [1 ]
机构：
[1] Univ Fukui, Dept Mat Sci & Engn, Fukui 9108507, Japan
来源：
SEN-I GAKKAISHI | 2011年 / 67卷 / 12期
关键词：
PRECURSOR GEL FIBERS; TRANSITION-METAL TI; ELECTROSPINNING PROCESS; POLYMER NANOFIBERS; THIN-FILMS; NANOCOMPOSITES; FABRICATION; NB; ZR;
D O I：
10.2115/fiber.67.261
中图分类号：
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号：
0805 ; 080502 ; 0821 ;
摘要：
Poly(vinyl alcohol)-titanium lactate hybrid nanofibers (precursors) were formed by electrospinning employing water as a solvent for the spinning solution. The precursors were converted into titanium carbide (TiC) or nitride (TiN) nanofibers by heating them in Ar or N-2 atmospheres. TiC nanofibers could be obtained below theoretical temperature calculated from thermodynamics data, indicating that metal and carbon sources were intimately mixed together. TiN nanofibers also could be obtained near theoretical temperature under N-2 gas flow. (Received 23 June, 2011; Accepted 8 August, 2011)
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页码：261 / 265
页数：5
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