Selective Adsorption of Water, Methanol, and Ethanol by Naphthalene Diimide-Based Coordination Polymers with Constructed Open Cu2+ Metal Sites and Separation of Ethanol/Acetonitrile

被引：9
作者：
Li, Guo-Bi [1 ]
Song, Bai-Qiao [2 ]
Wang, Shi-Qiang [2 ]
Pei, Ling-Min [3 ]
Liu, Sheng-Gui [1 ]
Song, Jiang-Li [1 ]
Yang, Qing-Yuan [4 ]
机构：
[1] Lingnan Normal Univ, Sch Chem & Chem Engn, Zhanjiang 524048, Peoples R China
[2] Univ Limerick, Bernal Inst, Dept Chem Sci, Limerick V94 T9PX, Ireland
[3] Xi An Jiao Tong Univ, Sch Sci, Dept Appl Chem, Xian 710049, Peoples R China
[4] Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
来源：
ACS OMEGA | 2019年 / 4卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ACETONITRILE; STORAGE; CHROMATOGRAPHY; CHEMISTRY; SOLVENT;
D O I：
10.1021/acsomega.8b03229
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The selective separation of ethanol/acetonitrile by porous materials has rarely been observed owing to their similar physicochemical properties. In this work, we report a new coordination network, [Cu-2(4-pmntd)(2)(opd)(2)](4-pmntd = N, N'-bis(4-pyridymethy) naphthalene diimide, opd = disodium 1,2-benzenedicarboxylate), which exhibits selective separation of ethanol over acetonitrile. The weak coordination bonds formed by unsaturated Cu2+ sites and hydroxyl groups are the key to such performance.
引用
收藏
页码：1995 / 2000
页数：6
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